TABLE 1.
Position |
1a |
2b |
||||||
δC | Type | δH, | mult (J in Hz) | δC | Type | δH, | mult (J in Hz) | |
1 | 173.8 | C | 173.3 | C | ||||
2 | 34.1 | CH2 | 2.30 | t (7.7) | 34.3 | CH2 | 2.30 | t (7.0) |
3 | 24.9 | CH2 | 1.60 | m | 24.9 | CH2 | 1.60 | m |
4–10 | 30.0-27.1 | CH2 | 1.31-1.23 | m | 30.0-27.1 | CH2 | 1.31-1.23 | m |
11 | 36.6 | CH2 | 1.27, 1.07 | m | 36.6 | CH2 | 1.27, 1.07 | m |
12 | 34.4 | CH | 1.28 | m | 34.4 | CH | 1.28 | m |
12-Me | 19.2 | CH3 | 0.83 | t (6.5) | 19.2 | CH3 | 0.84 | t (6.5) |
13 | 29.5 | CH2 | 1.25, 1.12 | m | 29.5 | CH2 | 1.25, 1.12 | m |
14 | 11.4 | CH3 | 0.84 | t (7.2) | 11.4 | CH3 | 0.85 | t (7.2) |
1′ | 64.5 | CH2 | 4.11 | m | 59.8 | CH2 | 3.73 | d (5.3) |
2′ | 69.1 | CH | 3.98 | m | 72.5 | CH | 4.97 | m |
3′ | 68.1 | CH2 | 4.00, 3.90 | m | 63.4 | CH2 | 4.08 | m |
1″″ | 61.6 | CH2 | 4.19 | m | 61.2 | CH2 | 4.20 | m |
2″ | 49.7 | CH2 | 3.15 | m | 49.9 | CH2 | 3.14 | m |
2″-NH | 9.64 | br s | 9.73 | br s | ||||
2″-N-Me | 33.6 | CH3 | 2.70 | s | 33.7 | CH3 | 2.71 | s |
a1H and 13C NMR were recorded at 800 MHz and 200 MHz, respectively.b1H and 13C NMR were recorded at 850 MHz and 212.5 MHz, respectively.