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. 2020 Oct 24;25(21):4923. doi: 10.3390/molecules25214923

Table 1.

Composition of P. graveolens obtained by hydrodistillation (HD), Porapak Q (HSD-P) and peat (HSD-T).

Compound Groups RI # RI-lit ## Content (%) **
HD HSD-T HSD-P
- Monoterpenes hydrocarbons - - 0.00 2.72 5.92
1 α-pinene 931 932 0.00 *a 0.00 a 4.14 ± 2.00 b
2 myrcene 988 988 0.00 a 0.00 a 0.51 ± 0.02 b
4 limonene 1028 1024 0.00 a 2.72 ± 1.10 b 0.00 a
5 (E)-β-ocimene 1046 1044 0.00 a 0.00 a 1.27 ± 0.33 b
- Oxygenated monoterpenes - - 65.50 66.32 38.69
6 linalool 1099 1095 11.19 ± 1.12 b 0.00 a 0.68 ± 0.12 a
7 (Z)-rose oxide 1109 1106 0.38 ± 0.05 b 0.00 a 2.47 ± 0.04 c
8 (E)-rose oxide 1126 1122 0.00 a 0.00 a 0.71 ± 0.07 b
9 isomenthone 1164 1158 1.27 ± 0.13 b 0.00 a 3.59 ± 0.52 c
10 citronellol 1226 1223 27.63 ± 0.48 a 28.06 ± 5.72 a 16.88 ± 0.02 a
11 neral 1238 1235 0.66 ± 0.06 b 0.00 a 0.00 a
12 geraniol 1250 1249 23.07 ± 1.63 b 38.26 ± 2.05 c 13.63 ± 1.35 a
13 geranial 1267 1264 1.30 ± 0.22 c 0.00 a 0.73 ± 0.03 b
- Sesquiterpenes hydrocarbons - - 9.70 15.25 37.95
16 α-copaene 1373 1374 0.00 a 0.00 a 1.36 ± 0.19 b
17 β-borbonene 1382 1387 0.40 ± 0.04 b 0.00 a 2.76 ± 0.21 c
18 (E)-caryophyllene 1418 1417 1.70 ± 0.25 b 0.00 a 4.76 ± 0.38 c
19 α-guaiene 1434 1437 0.00 a 0.00 a 1.44 ± 0.02 b
20 6,9-guaiadiene 1439 1442 4.98 ± 0.62 a 9.55 ± 3.54 b 16.98 ± 0.40 c
21 cis-muurola-3,5-diene 1448 1448 0.00 a 0.00 a 0.95 ± 0.01 b
22 α−humulene 1454 1452 0.40 ± 0.06 a 0.00 a 0.49 ± 0.43 a
24 γ-muurolene 1479 1478 1.16 ± 0.24 a 4.32 ± 1.64 b 6.64 ± 0.32 b
25 germacrene D 1484 1484 0.00 a 0.00 a 0.10 ± 0.18 a
26 bicyclogermacrene 1493 1500 0.44 ± 0.08 a 0.00 a 2.47 ± 0.32 b
27 δ-amorphene 1516 1511 0.62 ± 0.15 a 1.38 ± 1.27 a 0.00a
- Esters - - 18.77 13.74 15.24
3 (3Z)-hexenyl acetate 1005 1004 0.00 a 0.00 a 1.51 ± 0.20 b
14 citronellyl formate 1272 1271 9.41 ± 0.35 b 1.92 ± 1.77 a 6.95 ± 0.75 b
15 geranyl formate 1297 1298 3.92 ± 0.15 b 0.00 a 4.99 ± 0.29 c
23 linalool isovalerate 1468 1466 0.96 ± 0.03 b 0.00 a 0.00 a
28 geranyl butanoate 1554 1562 2.01 ± 0.12 a 3.30 ± 3.60 a 0.63 ± 0.55 a
29 2-phenyl ethyl tiglate 1582 1584 0.50 ± 0.45 a 0.00 a 0.23 ± 0.40 a
30 (E)- citronellyl tiglate 1662 1666 0.00 a 0.31 ± 0.54 a 0.00 a
31 geranyl tiglate 1694 1696 1.97 ± 0.11 a 8.21 ± 2.25 b 0.93 ± 0.03 a
Total 93.97 98.03 97.80

Means followed by the same lowercase letter in the line do not differ between themselves by the Tukey test (p < 0.05). * Values are mean of three independent experiments. ** Percentages obtained by flame ionization (FID) peak area normalization. # Retention index relative to C9–C19 n-alkanes on the DB-5MS column. ## Retention index from the literature Adams (2007).