Table 1.
Transition metal complexes with the carbones 1a to 1e including C-M and P-C bond lengths and P-C-P angles and 31PNMR shifts in ppm.
| 1-M | 31P NMR | C-M | P-C | P-C-P | Ref |
|---|---|---|---|---|---|
| Transition metal complexes with the carbone 1a | |||||
| 1a-Ni(CO)2 | 19.20 | 1.990(3) | 1.677(3) 1.676(3) | 132.13(16) | [39] |
| 1a-Ni(CO)3 | 9.92 | 2.110(3) | 1.681(3) 1.674(3) | 124.58(19) | [39] |
| 1a-ZnI2 | 17.8 | 2.000(9) | 1.691(9) 1.703(8) | 128.3(6) | [40] |
| 1a-CdI(μ I2)CdI-1a | 18.5 | 2.25(1) | 1.700(9) 1.68(1) | 124.8(7) | [40] |
| [1a-Hg-1a][Hg2Cl6] | 21.2 | 2.057(6) 2.082(7) | 1.731(6) 1.706(6) 1.737(6) 1.702(7) | 124.2(4) 125.7(3) | [41] |
| [1a-Ag-1a]I | 13.6 | 2.115(8) 2.134(7) | 1.656(7) 1.690(7) 1.667(7) 1.663(7) | 128.5(5) 129.1(5) | [42] |
| [1a-Cu-1a]I | 15.8 | 1.944(5) 1.951(5) | 1.683(6) 1.688(6) 1.673(6) 1.694(5) | 125.6(3) 128.3(3) | [41] |
| [1a-ReO3][ReO4] | 29.5 | 1.997(7) | 1.771(8) | 123.1(4) | [43] |
| 1a-CuCl | 16.5 | 1.906(2) | nr | 123.8(1) | [44] |
| 1a-Cu-C5H5 | 8.5 | nr | nr | nr | [45] |
| 1a-Cu-C5Me5 | 7.5 | 1.922(6) | 1.668(5) 1.660(6) | 136.0(4) | [45] |
| 1a-CuPPh3 | 3.7 | nr | nr | nr | [45] |
| 1a-AgCl | 16.5 | nr | nr | nr | [44] |
| 1a-AgCp* | 6.5 | nr | nr | nr | [45] |
|
1a-Au-C≡C-R R = C6H4NO2-p |
nr | 2.082(2) | 1.688(2) 1.682(2) | 133.64(13) | [46] |
| 1a-Au-CH(COMe)2 | nr | nr | nr | nr | [46] |
| 1a-AuCl | 13.7 14.4 | nr | nr | nr | [44] |
| [1a-Ir(COD)]PF6 | nr | nr | nr | nr | [47] |
| 1a-VCl3 | 21.13 | 2.050(3) | 1.712(2) 1.722(2) | 123.6(2) | [48] |
| 1a-FeCl (μ Cl2)FeCl-1a | par | 2.043(7) | 1.689(7) 1.712(7) | 121.3(4) | [49] |
| 1a-Fe[N(SiMe3)2]2 | par | 2.147(2) | 1.702(2) 1.720(2) | 120.0(1) | [50] |
| 1a-FeCl2 | par | 2.055(8) | 1.709(7) 1.702(7) | 122.7(5) | [49] |
| 1a-Fe(CH2Ph)2 | par | 2.097(5) | 1.694(5) 1.671(5) | 124.5(3) | [49] |
| 1a-FeCl[N(TMS)2] | par | nr | nr | nr | [49] |
| 1a-FeOTf[N(TMS)2] | par | 2.040(3) | 1.701(3) 1.704(3) | 122.1(2) | [49] |
| 1a-UCl4 | nr | 2.411(3) | 1.705(3) 1.719(3) | 125.05(16) | [51] |
| 1a-(AuCl)2 | 21.2 | 2.078(3) 2.074(3) | 1.776(3) 1.776(3) | 117.30(15) | [46] |
| [1aH-Ag-1aH](BF4)3 | 23.6 | 2.221(5) | 1.770(7) 1.779(7) | 119.9(4) | [52] |
| [1aH-Au-1aH](OTf)3 | 26.1 | nr | nr | nr | [46] |
| [1aH-AuCl](OTf) | 22.1 | nr | nr | nr | [46] |
| Transition metal complexes with the carbone 1b | |||||
| 1b-Fe[N(SiMe3)2]2 | par | 2.100(2) | 1.694(2) 1.696(1) | 120.8(9) | [50] |
| 1b-Ni(CO)3 | 2.6 | 2.091(2) | 1.683(2) 1.673(2) | 122.3(1) | [53] |
| 1b-Ni2(CO)5 | 12.1 | 2.080(5) 2.070(5) |
1.742(5) 1.743(5) | 117.1(3) | [53] |
| [1bH-AuC6F5](CF3SO3) | 22.7 | 2.029(6) | 1.781(2) 1.792(2) | 119.1 | [54] |
| [1bH-AuCl](CF3SO3) | 22.1 | nr | nr | nr | [54] |
| Transition metal complexes with the carbone 1c | |||||
| [1c-W(CO)2(Tp*)]PF6 | 36 | 2.11(1) | 1.75(2) 1.77(1) | 114.5(8) | [55] |
| 1c-(AuMe)2 | nr | nr | nr | nr | [56] |
| Transition metal complexes with the carbone 1d | |||||
| 1d-Ni(CO)3 | 3.5 | 2.0661(9) | 1.712(2) 1.722(2) | 117.19(9) | [48] |
| Transition metal complexes with the carbone 1e | |||||
| 1e-ZnCl2 | 28.9 | 1.994(2) | 1.686(2) | 125.3(1) | [32] |
| 1e-Rh(CO)(acac) | 32.9 | 2.092(3) | 1.685(3) | 128.56(17) | [32] |