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Transition metal complexes with the mixed carbones 11a and 11b. 31P NMR shifts in ppm.
| 11-M | 31P NMR | M-C | P-C C-C | P-C-C | Ref. |
|---|---|---|---|---|---|
| Transition metal complexes with the carbone 11a | |||||
| 11a-RhCl(CO)2 | 25.1 | nr | nr | nr | [98] |
| 11a-AuCl | 26.7 | 2.014(16) | 1.7449(16) 1.362(2) | 114.30(12) | [98] |
| 11a-(AuCl)2 | 28.1 | 2.081(4) 2.103(4) | 1.785(4) 1.425(6) | 114.2(3) | [98] |
| Transition metal complexes with the carbone 11b | |||||
| 11b-AuCl | 22.2 | nr | nr | nr | [98] |
