Table 11.

Collection of transition metal complexes with the carbones 13a and 13b. ³¹P NMR signals (in ppm) are given.

13-M	31P NMR	M-C	P-C S-C	P-C-S	Ref
Transition metal complexes with the carbone 13a based on a P-C-S core
13a-AgCl	10.8	2.131	1.711 1.648	121.9	[100]
[13a-AuPPh3](OTf)	15.2	nr	nr	nr	[100]
[13a-(AuPPh3)2](OTf)2	29.7	nr	nr	nr	[100]
Transition metal complexes with the carbone 13b based on a P-C-S core
13b-AgCl	9.13	2.098	1.728 1.636	119.1	[100]
[13b-AuPh3](SbF6)	12.88	nr	nr	nr	[100]
[13b-(AuPPh3)2](SbF6)2	27.45	2.127 2.118	1.788 1.737	115.6	[100]
[13b-Ag-13b][OTf)	8.43	2.160	1.707 1.635	121.8 127.0	[100]
[13bH-AuPPh3](OTf)2	17.1	2.106	1.817 1.782	116.3	[100]