Table 14.
Selected structural (in Å and deg) and spectroscopic (13C NMR in ppm) details of [Ru]C addition compounds.
| 13C NMR | Ru-C | M-C | Ru-C-M | Ref | |
|---|---|---|---|---|---|
| [Ru]C→PdCl2(SMe2) | 381.23 | 1.662(2) | 1.946(2) | 175.1(1) | [109] |
| {[Ru]C→PdCl3}− | 380.9 | nr | nr | nr | [112] |
| [Ru]C→Mo(CO)5 | 446.31 | nr | nr | nr | [109] |
| [Ru]C→PtCl2Py | 350.34 | nr | nr | nr | [29,111] |
| [Ru]C→PtCl2NCr(dbm)2 | nr | 1.676(2) | 1.899(2) | 174.5(1) | [29] |
| {[Ru]C→PtCl3}− | 344.7 | nr | nr | nr | [29,112] |
| {[Ru]C→PtCl2}2 | 326.23 | 1.676(8) | 1.871(8) | 1796(4) | [29,111] |
| [Ru]C→PtCl2PPh3 | 388.81 | 1672(2) | 1.983(2) | 173.7(1) | [111] |
| [Ru]C→PtCl2P(OPh)3 | 387.54 | 1.659(2) | 2.001(2) | 179.3(2) | [111] |
| [Ru]C→PtCl2AsPh3 | 374.68 | 1.670(2) | 1.949(2) | 171.9(2) | [111] |
| [Ru]C→PtCl2CNtBu | 376.26 | 1.661(2) | 1.967(6) | 176.5(3) | [111] |
| [Ru]C→PtCl2CNCy | 376.04 | nr | nr | nr | [111] |
| [Ru]C→PtCl2PCy3 | 396.77 | 1.666(3) | 1.971(2) | 174.5(2) | [111] |
| [Ru]C→PtCl2(dmso) | 349.0 | [112] | |||
| {[Ru]C→PtCl2}2bipy | 348.27 | 1.679(3) | 1.891(4) | 171.4(2) | [111] |
| {[Ru]C→PtCl2}2pyz | 342.48 | 1.668(6) | 1.895(6) | 176.3(3) | [111] |
| {[Ru]C→PtCl2}2pym | 341.36 | 1.678(3) | 1.893(3) | 176.0(2) | [111] |
| {[Ru]C→PtCl}2(μ-Cl)pz | 355.09 | 1.678(4) | 1.909(4) | 169.9(2) | [111] |
| [Ru]C→AuCl | 395.3 | nr | nr | nr | [112] |
| {[Ru]C→Au←C[Ru]}+ | 395.3 | nr | nr | nr | [112] |
| {[Ru]C→IrCl(CO)←C[Ru]} | 397.4 | nr | nr | nr | [112] |
| {[Ru]C→Rh(CO)}2(μ-Cl)2 | 396.4 | nr | nr | nr | [112] |
| [Ru]C→RhCl(cod) | 411.7 | nr | nr | nr | [112] |
| [Ru]C→IrCl(cod) | 387.6 | nr | nr | nr | [112] |
| {[Ru]C→Ag(4′-H-terpy)} | 433.5 | nr | nr | nr | [112] |
| {[Ru]C→Ag(4′-Ph-terpy)} | 433.1 | nr | nr | nr | [112] |
| [Ru]C→Ag(ttcn) | nr | 1.653(4) | 1.876(4) | 177.3(2) | [112] |
| [Ru]C→Cu(ttcn) | nr | 1.622(7) | 2.098(7) | 176.9(5) | [112] |
| [Ru]C→Pd-S4(MoCp*)3 | nr | 1.672(3) | 1.971(3 | 178.3(2) | [112] |
| [Ru]C→Pt-S4(MoCp*)3 | nr | 1.689(7) | 1.896(7) | 178.2(5) | [112] |
| [Ru]C→Pd-S4(WCp*)3 | nr | 1.668(5) | 1.959(5) | 178.1(3) | [112] |
| [Ru]C→Pt-S4(WCp*)3 | nr | 1.699(9) | 1.874(9) | 178.8(6) | [112] |