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Compounds with [Mo]−C core with Tp* = [HB(pzMe2)3]− or [HB(pz)3]−.
| Mo-C | M-C | Mo-C-M | 13C NMR | Ref | |
|---|---|---|---|---|---|
| Tp* is [HB(pzMe2)3]− | |||||
| [Mo]C→FeCp(CO)2 | 1.819(6) | 1.911(8) | 172.2(5) | 381 | [117] |
| (μ-Se2)[Ir2-{[Mo]C}2(CO)2(PPh3)2] | 1.843(5) | 1.974(5) | 171.3(3) 168.2(3) | 286.1 | [119] |
| [Mo]C→Hg←C[Mo] | nr | nr | nr | 373 | [120] |
| [Mo]C→AuPPh3 | nr | nr | nr | nr | [122] |
| Tp* is [HB(pz)3]− | |||||
| [Mo]C→Pt(PPh3)2Br | nr | nr | nr | 339.0 | [121] |
