Table 3.

Measures of nonplanarity for Re corroles: the Re–N4 displacement (Å), the C8–C9–C11–C12 saddling dihedral (°), and the C5–Re–C15 angle (°).

Molecule	Re–N4 (Å)	χC8–C9–C11–C12 (°)	ϕC5–Re–C15 (°)
Re[TPC](O)	0.704	7.2	155.1
Re[Cl8TpCF3PC](O); molecule 1	0.671	15.4	155.1
Re[Cl8TpCF3PC](O); molecule 2	0.659	6.7	154.0
Re[Cl8TpCH3PC](O)	0.671	8.5	157.4
Re[Br8TpFPC](O)	0.668	11.9	152.5