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. Author manuscript; available in PMC: 2020 Nov 13.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Apr 23;59(33):13734–13762. doi: 10.1002/anie.201909690

Table 2:

Selected ABS methods using oxidative organic reactions (B).[a]

Primary Reaction Associated
Secondary Reactions
Analytes Associated Imaging
Modalities
Seminal
Refs./Reviews
graphic file with name nihms-1642682-t0021.jpg (formal) retro [2+2] cycloaddition 1O2 chemiluminescence 116
graphic file with name nihms-1642682-t0022.jpg Criegee fragmentation, b-elimination O3 fluorescence 117
graphic file with name nihms-1642682-t0023.jpg dehydration NO+O2 fluorescence 65
graphic file with name nihms-1642682-t0024.jpg dehydration, electrophilic aromatic substitution NO+O2 fluorescence 118
graphic file with name nihms-1642682-t0025.jpg 5-exo-tet cyclization, hydrolysis ONOO fluorescence 120, 121
graphic file with name nihms-1642682-t0026.jpg 5-exo-trig cyclization, trans-esterification HNO fluorescence 123
graphic file with name nihms-1642682-t0027.jpg dehydration, 5-exo-trig cyclization HNO fluorescence, chemiluminescence 124
graphic file with name nihms-1642682-t0028.jpg 5-exo-trig cyclization, thio-esterification RS-(S)n-SR, H2S2, or S8 fluorescence 128
HSnR (n>1); RSH, S8 129
[a]

EDG = electron-donating group.