. Author manuscript; available in PMC: 2020 Nov 16.

Published in final edited form as: Int J Mol Biol (Edmond). 2020 Jul 31;5(3):79–109.

Table 3.

Stern-Volmer quenching constants K_sv and k_q, and the binding parameters n and K_a, for each apo-hTf: Cp₂M(IV)Cl₂complex formed at four different temperatures

Compound	Temperature (K)	K_sv (×10⁴) (M⁻¹⁾	k_q (×10¹¹) (M^−1s−1)	n	K_a (×10⁴)(M⁻¹)
Cp₂VCl₂	296	3.564	35.64	1.23	44.44
	303	4.085	40.85	1.2	33.75
	310	4.26	42.6	1.16	24.05
	317	4.936	49.36	1.11	15.98
Cp₂NbCl₂	296	2.523	25.23	1.26	32.53
	303	2.804	28.04	1.27	40.81
	310	3.056	30.56	1.28	48.55
	317	3.323	33.23	1.29	56.23
Cp₂MoCl₂	296	0.151	1.51	1.26	1.93
	303	0.159	1.59	1.23	1.58
	310	0.181	1.81	1.19	1.21
	317	0.205	2.05	1.16	0.95
Cp₂WCl₂	296	0.161	1.61	1.16	0.78
	303	0.176	1.76	1.13	0.6
	310	0.189	1.89	1.08	0.42
	317	0.209	2.09	1.04	0.32
Cp₂TiCl₂	296	0.153	1.53	1.11	0.45
	303	0.168	1.68	1.09	0.41
	310	0.176	1.76	1.07	0.36
	317	0.193	1.93	1.05	0.31
Cp₂ZrCl₂	296	0.239	2.39	1.07	0.44
	303	0.197	1.97	1.03	0.26
	310	0.179	1.79	1.01	0.2
	317	0.15	1.5	1	0.16
Cp₂HfCl₂	296	0.197	1.97	1.15	0.89
	303	0.157	1.57	1.17	0.81
	310	0.136	1.36	1.18	0.75
	317	0.124	1.24	1.19	0.7
(NH₃)₂Pt(II)Cl₂	296	0.135	1.35	0.97	0.11
	303	0.11	1.1	1.01	0.12
	310	0.098	0.98	1.04	0.14
	317	0.086	0.86	1.07	0.16