Table 6.

Contents secondary structure elements (α-helix, β-sheet, and random coil) of apo-hTf in the presence and absence of seven Cp₂M(IV)Cl₂ and DCCP based on the Raussens et al.’s method (CD-RRG)

Compound	Secondary structure elements	Contents secondary structure of apo-hTf (%)
		Compound concentration (M)
		0	0.4	0.8	1.2	1.6	2	2.4
Cp2VCl2	α-helix	29	28.4	27.9	27.2	26.5	25.8	25.1
	β-sheet	17.7	17.9	18.1	18.3	18.5	18.9	19.2
	random coil	33.5	33.7	33.9	34.1	34.3	34.5	34.6
	other	19.8	20	20.1	20.4	20.7	20.8	21.1
Cp2NbCl2	α-helix	29.8	29	28.7	27.6	26.9	26.2	25.4
	β-sheet	17.3	17.7	17.9	18.5	18.9	19	19.4
	random coil	33.6	33.8	34	34.2	34.4	34.6	34.8
	other	19.3	19.5	19.4	19.7	19.8	20.2	20.4
Cp2MoCl2	α-helix	29.3	28.7	28.3	27.6	27.1	26.5	25.8
	β-sheet	17.9	18.1	18.3	18.4	18.6	18.9	19.3
	random coil	33.8	33.9	34	34.1	34.3	34.5	34.7
	other	19	19.3	19.4	19.9	20	20.1	20.2
Cp2WCl2	α-helix	30.2	29.8	29.5	29.1	28.3	27.9	27.5
	β-sheet	18.1	18.2	18.3	18.4	18.5	18.6	18.7
	random coil	33.5	33.7	33.8	33.9	34.1	34.3	34.4
	other	18.2	18.3	18.4	18.6	19.1	19.2	19.4
Cp2TiCl2	α-helix	29.5	29.3	29.1	29	28.8	28.6	28.4
	β-sheet	17.8	18	18.2	18.3	18.4	18.5	18.6
	random coil	33.8	33.8	33.8	33.9	33.9	34	34
	other	18.9	18.9	18.9	18.8	18.9	18.9	19
Cp2HfCl2	α-helix	29.8	29.7	29.5	29.3	29.1	29	28.7
	β-sheet	17.4	17.5	17.6	17.7	17.8	17.9	18
	random coil	33.6	33.7	33.8	33.8	34	34	34.1
	other	19.2	19.1	19.1	19.2	19.1	19.1	19.2
Cp2ZrCl2	α-helix	29.4	29.2	29.1	29	28.8	28.6	28.4
	β-sheet	18	18.1	18.2	18.3	18.4	18.5	18.6
	random coil	33.8	33.8	33.9	33.9	33.9	34	34.1
	other	18.8	18.9	18.8	18.8	18.9	18.9	18.9
(NH3)2Pt(II)Cl2	α-helix	29.2	28.9	28.7	28.5	28.3	28.1	28
	β-sheet	18	18.1	18.2	18.3	18.4	18.5	18.6
	random coil	33.9	33.9	33.9	34	34	34.1	34.1
	other	18.9	19.1	19.2	19.2	19.3	19.3	19.3
Crystallographic or far-UV CD data reported by:		96	109	108
apo-hTf	α-helix	31	32	41.5
	β-sheet	18	22	28.4
	random coil	51	46	30.1
	other