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. Author manuscript; available in PMC: 2021 Nov 16.
Published in final edited form as: Inorg Chem. 2020 Oct 30;59(22):16341–16360. doi: 10.1021/acs.inorgchem.0c02137

Table 5:

Singlet oxygen quantum yields in acetonitrile at room temperature. The excitation wavelength (in nm) is indicated in parentheses.

cmpd ΦΔ
LL=bpy; x=1 LL=dmb; x=2
[Os(LL)3]2+ 0.22 (479)a 0.13 (470)
x-0T 0.24 (475) 0.26 (470)
x-1T 0.16 (476) 0.20 (476)
x-2T 0.18 (475) 0.20 (472)
x-3T 0.21 (489) 0.15 (417)
x-4T 0.70 (460) 0.56 (461)
a

Literature value83