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. 2020 Nov 19;106:104488. doi: 10.1016/j.bioorg.2020.104488

Scheme 20.

Scheme 20

Final step in the total synthesis of avermectin B1a. HMPA = Hexamethylphosphoramide, TBAF = tetra-n-butylammonium fluoride, DTBMP = 2,6-di-tert-butyl-4-methylpyridine.