Table 2. Composition Ratio, Basicity, and CO2 Uptake Data of the Parent Chitosan and HTC Materials.
H/C | O/C | N/C | basicity (mmol·g–1) | CO2 uptake (mmol·g–1) | ΔG° (kJ·mol–1) | |
---|---|---|---|---|---|---|
CHIT | 0.17 | 1.15 | 0.18 | 5.9 | 0.10 | –6.43 |
CHIT-HTC-12 | 0.16 | 1.06 | 0.18 | 5.0 | 0.10 | –2.41 |
CHIT-HTC-24 | 0.15 | 0.97 | 0.16 | 3.6 | 0.30 | –3.63 |
CHIT-HTC-48 | 0.13 | 0.77 | 0.15 | 2.6 | 0.45 | –3.15 |
Langmuir |
Freundlich |
|||||
---|---|---|---|---|---|---|
KL (bar–1) | qm (mmol·g–1) | R2 | KF (mmol1–(1/n)·g1/n·g–1) | n | R2 | |
CHIT | 13.4 | 0.13 | 0.994 | 0.12 | 3.6 | 0.880 |
CHIT-HTC-12 | 2.6 | 0.17 | 0.928 | 0.13 | 2.4 | 0.954 |
CHIT-HTC-24 | 4.3 | 0.40 | 0.974 | 0.34 | 3.1 | 0.980 |
CHIT-HTC-48 | 3.6 | 0.55 | 0.978 | 0.44 | 2.6 | 0.995 |
pseudo-first order |
pseudo-second order |
|||||
---|---|---|---|---|---|---|
qe (mmol g–1) | k1 (min–1) | R2 | qe (mmol·g–1) | k2 (g·mmol–1·min–1) | R2 | |
CHIT | 0.10 | 0.78 | 0.992 | 0.11 | 15.3 | 0.999 |
CHIT-HTC-12 | 0.16 | 0.76 | 0.991 | 0.14 | 6.8 | 0.996 |
CHIT-HTC-24 | 0.33 | 0.76 | 0.991 | 0.34 | 3.7 | 0.997 |
CHIT-HTC-48 | 0.44 | 0.77 | 0.992 | 0.47 | 3.2 | 0.999 |