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. 2020 Nov 3;5(45):29520–29529. doi: 10.1021/acsomega.0c04470

Table 2. Composition Ratio, Basicity, and CO2 Uptake Data of the Parent Chitosan and HTC Materials.

  H/C O/C N/C basicity (mmol·g–1) CO2 uptake (mmol·g–1) ΔG° (kJ·mol–1)
CHIT 0.17 1.15 0.18 5.9 0.10 –6.43
CHIT-HTC-12 0.16 1.06 0.18 5.0 0.10 –2.41
CHIT-HTC-24 0.15 0.97 0.16 3.6 0.30 –3.63
CHIT-HTC-48 0.13 0.77 0.15 2.6 0.45 –3.15
  Langmuir
Freundlich
  KL (bar–1) qm (mmol·g–1) R2 KF (mmol1–(1/n)·g1/n·g–1) n R2
CHIT 13.4 0.13 0.994 0.12 3.6 0.880
CHIT-HTC-12 2.6 0.17 0.928 0.13 2.4 0.954
CHIT-HTC-24 4.3 0.40 0.974 0.34 3.1 0.980
CHIT-HTC-48 3.6 0.55 0.978 0.44 2.6 0.995
  pseudo-first order
pseudo-second order
  qe (mmol g–1) k1 (min–1) R2 qe (mmol·g–1) k2 (g·mmol–1·min–1) R2
CHIT 0.10 0.78 0.992 0.11 15.3 0.999
CHIT-HTC-12 0.16 0.76 0.991 0.14 6.8 0.996
CHIT-HTC-24 0.33 0.76 0.991 0.34 3.7 0.997
CHIT-HTC-48 0.44 0.77 0.992 0.47 3.2 0.999