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. 2020 Nov 4;142(46):19473–19479. doi: 10.1021/jacs.0c10092

Figure 4.

Figure 4

(A) Oxidation of bismuthinidine 5 with N2O; (B) ORTEP drawing of 7, with ellipsoids drawn at the 50% probability level. H atoms except H1, H8s, and H10s and the enantiomer of 7 in the unit cell are omitted for clarity. Selected bond lengths (Å) and angles (deg): Bi1–C1 2.1869(11), Bi1–O1 2.0984(10), Bi1–N1 2.2319(9), Bi1–N2 2.6117(9), N1–C7 1.3832(15), N2–C9 1.2848(14), C7–C8 1.3552(16), C9–C10 1.4969(16), C1–Bi1–O1 94.68(4).