Skip to main content
. 2020 Nov 4;142(46):19540–19550. doi: 10.1021/jacs.0c07381

Scheme 5. (A) Hillhouse I2-Promoted C(sp3)–O–C(sp3) Bond Formation Reaction (Analysis of the Fate of the Organic and Inorganic Compounds); (B) X-ray Structure of Complex 8;31 (C) NiIII Bimetallic Intermediate 9a–b; (D) 1H NMR of Paramagnetic Complex 9a(31).

Scheme 5

Disordered iodine atoms are omitted for clarity. Selected distances (Angstroms): Ni1–I1 = N2–I2 = 2.78; Ni1–I2 = Ni2–I1 = 2.83; Ni1–N1 = Ni1–N2 = 2.07. Selected angles (degrees): I1–Ni–I2 = 89.2; Ni1–I1–Ni2 = 94.2.

Insets correspond to peaks at 237, −98, and −930 ppm.