Table 1.

Compounds identified by UPLC-ESI-TOFMS/MS in positive mode in the CE of A. cearensis seeds

Peak no.	Retention time (min)	[M-H]− observed	[M-H]− calculated	Product ions (MS/MS)	Empirical formula	Parts per million (error)	Putative name	References
1	1.18	689.2051	689.2082	689.2087, 367.1008, 352.8637	C33H37O16	4.5	Icariin glucuronide	Shunjun et al. (2017)
2	1.29	527.1564	527.1553	202.1848, 184.9314, 178.0209	C27H27O11	2.1	QQCA (quinicquinic-caffeic acid ester)	Plazonić et al. (2009)
3	2.94	467.1732	467.1706	329.0866, 261.0790, 179.0338, 137.0256	C21H23O12	2.2	(Epi)gallocatechin hexose II	Ibrahim et al. 2014
4	3.11	305.0735	305.0720	179.0339, 167.0341, 137.0252, 125.0241	C15H13O7	4.9	Gallocatechin	Ibrahim et al. (2014)
5	3.32	172.0376	172.0372	242.9876, 144.0423, 116.0501	C6H2N7	2.3	No identified	–
6	4.93	218.2143	218.2120	177.0513, 145. 0170, 225.9959	C12H28NO2	10.5	No identified	–
7	6.09	246.2422	246.2433	258.8799, 184.0619, 156.0619	C14H32NO2	4.5	No identified	–
8	7.25	247.2733	247.2746	275.2783, 256.2661, 230.2536	C16H36NO2	4.7	No identified	–
9	7.96	283.1002	283.1029	295.0207, 240.0207, 133.0802	C16H12O5	9.5	Dihydroxymethoxyisoflavone	Oliveira et al. (2017)
10	8.26	119.0829	119.0821	437.2041, 185.1608, 120.0852	C4H11N2O2	6.7	No identified	–
11	8.46	303.0885	303.0874	137.0244	C16H15O6	3.6	4′- or 5′-O-Methyl-(epi)catechin I	Ibrahim et al. (2014)
12	9.27	393.3636	393.3639	334.3075, 249.1913,133.0866	C13H41N14	0.8	No identified	–
13	9.69	332.3412	332.28	330.3311, 270.9351, 150.7104		1.0	Gallic-caffeic acid ester	Plazonić et al. (2009)
14	9.84	457.2762	457.2743	155.0720, 458.2881	C31H37O3	4.2	No identified	–
15	9.89	457.2829	457.2801	155.0675, 458.2868	C24H41O8	6.1	No identified	–