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. 2020 Nov 4;9(11):1083. doi: 10.3390/antiox9111083

Table 1.

Chemical composition of commercial Thymus vulgaris essential oil.

# a RI Lit b RI Exp c Class/Compound d % e
Monoterpene hydrocarbons 29.45
2 927 923 Tricyclene 0.07
3 930 927 α-Thujene 0.30
4 939 934 α-Pinene 1.52
5 954 949 Camphene 1.73
7 991 988 β-Myrcene 1.63
8 1003 1001 α-Phellandrene 0.12
9 1017 1015 α-Terpinene 0.89
10 1025 1025 p-Cymene 19.20
11 1029 1028 Limonene 0.48
13 1060 1058 γ-Terpinene 3.43
16 1089 1085 Terpinolene 0.08
Oxygenated monoterpenes 59.95
12 1031 1031 1,8-Cineole 1.44
14 1070 1067 cis Sabinene hydrate 0.11
15 1073 1072 trans Linalool oxide 0.06
17 1097 1096 Linalool 5.67
18 1146 1141 Camphor 1.05
19 1153 1149 Menthone 1.08
20 1169 1163 Borneol 1.79
21 1172 1169 Menthol 0.48
22 1177 1174 Terpinen-4-ol 1.97
23 1183 1186 <iso>-Menthol 0.10
24 1189 1190 α-Terpineol 0.11
25 1235 1227 Thymol methyl ether 0.37
26 1245 1237 Carvacrol methyl ether 0.51
27 1238 1245 Neral 0.05
28 1242 1249 Carvone 0.31
29 1291 1281 p-Cymen-7-ol 0.05
30 1290 1295 Thymol 42.10
31 1299 1300 Carvacrol 2.70
Sesquiterpenes 7.93
32 1351 1344 α-Cubebene 0.05
34 1377 1369 α-Copaene 0.15
35 1419 1411 β-Caryophyllene 6.40
36 1466 1450 <9-epi-(E)>-Caryophyllene 0.05
37 1485 1481 Germacrene D 0.08
38 1514 1500 γ-Cadinene 0.06
39 1523 1506 δ-Cadinene 0.23
40 1583 1568 Caryophyllene oxide 0.80
41 1670 1652 <14-Hydroxy-9-epi-(E)>-Caryophyllene 0.11
Others 1.32
1 855 858 3-Hexen-1-ol 0.23
6 979 978 1-Octan-3-ol 0.87
33 1359 1350 Eugenol 0.22

a The numbering refers to elution order; b Literature retention index (RI); c Retention index (RI) relative to a standard mixture of n-alkanes on SPBTM-5 column; d Identified compounds (<0.05% have not been reported); e Relative peak area percent represent averages of 3 determinations.