Table 3.
Ageing Time (Days) | |||||||||
---|---|---|---|---|---|---|---|---|---|
Volatile Compound | m/z | LRI | 1 | 3 | 6 | 9 | 14 | SEM | p-Value |
2,3-Butanedione | 43 | 592 | 203.73 | 165.32 | 145.96 | 94.94 | 123.05 | 39.25 | 0.586 |
2-Butanone | 72 | 596 | 61.77 | 47.36 | 69.32 | 103.30 | 56.65 | 2.36 | 0.096 |
2-Pentanone | 86 | 720 | 19.67 | 16.61 | 16.78 | 14.93 | 16.86 | 1.90 | 0.568 |
3-Pentanone | 57 | 736 | 77.94 | 86.39 | 87.04 | 46.35 | 83.31 | 1445.53 | 0.447 |
2,3-Pentanedione | 100 | 739 | 76.16 a | 161.23 b | 137.75 a,b | 99.43 a,b | 149.03 a,b | 20.34 | 0.011 |
Acetoin | 45 | 787 | 1735.75 | 1540.13 | 1392.70 | 790.07 | 436.27 | 7.06 | 0.149 |
2-Hexanone | 58 | 863 | 52.48 a | 38.46 a,b | 19.55 b | 27.82 a,b | 26.74 a,b | 0.80 | 0.016 |
3-Heptanone | 57 | 960 | 22.90 | 32.27 | 31.33 | 30.30 | 34.04 | 7.75 | 0.607 |
2-Heptanone | 58 | 967 | 1055.89 | 1285.42 | 648.08 | 943.32 | 1023.91 | 9.22 | 0.239 |
4-Cyclopentene-1,3-dione | 96 | 1003 | 39.23 | 71.76 | 65.49 | 56.37 | 50.62 | 545.25 | 0.175 |
4-Hexen-3-one, 5-methyl- | 83 | 1047 | 54.19 | 39.88 | 25.56 | 29.30 | 34.18 | 3.23 | 0.148 |
Butyrolactone | 42 | 1049 | 87.11 | 61.90 | 78.59 | 84.56 | 79.82 | 2.10 | 0.346 |
2(5H)-Furanone | 55 | 1053 | 259.73 | 129.48 | 80.36 | 265.89 | 50.97 | 91.23 | 0.282 |
3-Octen-2-one | 55 | 1111 | 48.42 | 70.55 | 37.78 | 42.52 | 73.75 | 4.79 | 0.083 |
3-Octanone, 2-methyl- | 43 | 1141 | 32.40 a | 62.72 a,b | 45.55 a,b | 34.68 a,b | 64.55 b | 3.62 | 0.012 |
2-Nonanone, 3-(hydroxymethyl)- | 43 | 1146 | 15.27 | 17.35 | 19.34 | 22.43 | 17.61 | 4.39 | 0.404 |
Total Ketones | 4210.12 | 2888.86 | 1347.94 | 2342.08 | 913.27 | 38.21 | 0.080 |
Different letters in the same line show statistical differences (a,b: p < 0.01). SEM: standard error of mean; m/z: Quantifier ion; LRI: Lineal Retention Index calculated for DB-624 capillary column (J&W scientific: 30 m × 0.25 mm id, 1.4 µm film thickness) installed on a gas chromatograph equipped with a mass selective detector. LRI: linear retention index in agreement with literature for the same chromatographic column [25,34,43].