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. 2020 Nov 17;25(22):5373. doi: 10.3390/molecules25225373

Scheme 26.

Scheme 26

Cycloaddition of dimethyl acetylenedicarboxylate to 3,10-dimethyl- and 3,10-dihexylperylene [182]. Reagents and conditions: (a) p-chloranil, PhNO2, rfx, 2 h; R = Me (45% overall yield; 115:117 = 3:1); R = n-C6H13 (15% overall yield; 116:118 = 2:1).