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(a) Coordination modes of carboxylate ligands in complex 2; (b) a fragment of the 1D crystal structure merged with 2C1 underlying net in valence-bonded MOFs standard representation and a fragment of the 2D crystal structure merged with hcb underlying the net in H-bonded MOFs standard representation for coordination polymer 2 (Bi—orange, O—red, N—blue, Cl—green, C—black, H—white).
