Table 8.
The kinetics study results corresponding to Figure 12.
Models | Parameter | Value | |
---|---|---|---|
Pseudo-first order (PFO) |
K1 (min−1) | 0.021 | |
qe (mg/g) | 8.868 | ||
R2 | 0.889 | ||
Pseudo-second order (PSO) Where K2 is rate constant (g·mg−1·min−1) |
K2 (g·mg−1·min−1) | 0.162 | |
qe(mg/g) | 13.94 | ||
R2 | 0.999 | ||
Elovich equation is is used to predict the sorption mechanism, where qt is adsorbed quantity at time t; while α and β are initial sorption concentration rate (mg·g−1·min−1), and desorption constant (g/mg), respectively. | Α | 7.1 × 103 | |
Β | 0.392 | ||
R2 | 0.978 | ||
Weber-Morris intraparticle diffusion model is used to study the formed layers around the adsorbent and rate-controlling step, which is expressed as , where KI is intraparticle diffusion rate constant (mg·g−1·min−0.5), and C is the boundary thickness effect. | KI | 2.19 | 0.55 |
C | 19.02 | 26.16 | |
R2 | 0.934 | 0.898 |