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Activation of (A) alkanes and (B) aromatics through fumarate addition and their biodegradation under anaerobic conditions. AssABC, alkylsuccinate synthase; Mcm, methylmalonyl-CoA mutase; BssABC, benzyl-succinate synthase; Bcr/Bam, benzoyl-CoA reductase; Dch/BamR, dienoyl-CoA hydratase; Had/BamQ, hydroxyacyl-CoA dehydrogenase; Oah/BamA, oxoacyl-CoA hydrolase; Fdox, oxidized ferredoxin; Fdred, reduced ferredoxin.
