Table 1.
Starting decomposition temperatures, IL weight loading, and remaining sample amount at 1,073 K of all the materials used and produced in this work, obtained by TGA.
| Sample | Tstart (K) | IL loading (wt.%) | Experimental remaining | Calculated remaining sample |
|---|---|---|---|---|
| sample amount (wt.%) | amount (wt.%)a | |||
| ZIF-8 | 690 | 0.0 | 63 | — |
| Neat [C4MIM]2[NiCl4] | 531 | — | 11 | — |
| [C4MIM]2[NiCl4]@ZIF-8 | 460 | 17.7 | 52 | 54 |
| Neat [C4MIM]2[MnCl4] | 510 | — | 21 | — |
| [C4MIM]2[MnCl4]@ZIF-8 | 456 | 17.6 | 50 | 56 |
| Neat [C4MIM]2[CoCl4] | 534 | — | 6 | — |
| [C4MIM]2[CoCl4]@ZIF-8 | 538 | 17.7 | 52 | 53 |
| Neat [C4MIM]2[Co(NCS)4] | 529 | — | 19 | — |
| [C4MIM]2[Co(NCS)4]@ZIF-8 | 533 | 20.4 | 53 | 54 |
| Neat [C4MIM][FeCl4] | 591 | — | 10 | — |
| [C4MIM][FeCl4]@ZIF-8 | 471 | 13.2 | 52 | 56 |
a
Calculated from Equation (3), at 1,073 K.