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. Author manuscript; available in PMC: 2020 Nov 30.
Published in final edited form as: Chem Rev. 2020 Mar 16;120(12):5082–5106. doi: 10.1021/acs.chemrev.9b00556

Figure 11.

Figure 11.

35 GHz 1H stochastic-field modulation detected (stochastic CW) ENDOR spectra of E4(4H) in 70Val→Ile/α−195His→Gln MoFe protein, acquired at g = 1.991 and 1.964 (black) and summed simulations (red). The signal with ν0(1H) ± ~3 MHz, with both positive and negative features, represents transient responses from weakly coupled, more distant protons. Reproduced with permission ref 150. Copyright 2019 American Chemical Society.