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. 2020 Oct 16;83(11):3250–3261. doi: 10.1021/acs.jnatprod.0c00499

Table 2. 13C NMR (125 MHz) Data for Compounds 1–11a.

  δc, type
position 1a+d 1b+c 2a 2b 3 4a+b 5 6a 6b 7a+b 8 9 10 11
1 83.8, C 83.1, C 133.0, C 132.8, C 83.5, C 122.0, C 132.5, C 83.2, C 82.4, C 121.8, C 82.5, C 121.9, C 81.9, C 121.8, C
1a 157.2, C 157.0, C 150.9, C 154.4, C 145.1, C 133.9, C 152.0, C 157.9, C 157.5, C 139.1, C 144.2, C 141.0, C 147.3, C 139.2, C
2 202.6, C 202.4, C 185.4, C 184.7, C 202.4, C 155.8, CH 185.3, C 202.7, C 202.5, C 155.5, C 202.9, C 156.3, C 201.4, C 155.5, C
3 125.9, CH 125.9, CH 131.9, CH 131.8, CH 124.1, CH 113.8, CH 131.2, CH 125.8, CH 125.8, CH 113.7, CH 124.6, CH 114.2, CH 125.1, CH 113.6, CH
4 139.7, CH 139.7, CH 144.8, CH 146.5, CH 143. 6, CH 124.6, CH 145.6, CH 139.6, CH 139.6, CH 124.5, CH 139.8, CH 125.7, CH 142.7, CH 124.6, CH
4a 125.4, C 125.4, C 73.1, C 77.3, C 123.7, C 125.2, C 73.0, C 125.0, C 125.0, C 125.5, C 123.7, C 126.0, C 131.0, C 125.5, C
5 123.1, CH 123.1, CH 131.0, CH 128.8, CH 139.9, C 122.2, CH 130.6, CH 122.6, CH 122.6, CH 121.8, CH 103.3, CH 117.3, CH 94.6, C 121.7, CH
5a 151.9, C 151.9, C 159.6, C 156.8, C 122.9, C 156.7, C 160.5, C 152.7, C 152.9, C 157.7, C 130.7, C 150.6, C 136.1, C 157.8, C
6 185.9, C 185.9, C 186.2, C 186.1, C 147.8, C 186.5, C 186.3, C 185.9, C 186.0, C 186.6, C 154.0, C 202.6, C 194.4, C 186.7, C
7 135.8, C 135.8, C 134.1, C 133.9, C 125.2, C 135.7, C 133.8, C 135.2, C 135.3, C 135.1, C 124.4, C 82.1, C 130.4, C 135.1, C
8 149.6, C 149.6, C 150.2, C 153.6, C 134.1, C 149.6, C 150.7, C 150.2, C 150.4, C 150.6, C 138.2, C 145.9, C 147.9, C 150.5, C
8a 73.2, C 73.2, C 75.1, C 76.7, C 127.9, C 73.8, C 74.5, C 72.7, C 72.7, C 73.4, C 127.3, C 131.6, C 132.6, C 73.2, C
9 33.1/34.0, CH2b 33.1/34.0, CH2b 34.3, CH2 41.1, CH2 129.7, CH 34.5, CH2 34.1, CH2 33.2, CH2 34.2, CH2 34.8, CH2 129.0, CH 25.8/26.6, CH2b 129.0, CH 34.8, CH2
10 21.8, CH2 22.4, CH2 22.8, CH2 22.7, CH2 121.3, CH 23.9, CH2 22.9, CH2 21.9, CH2 22.5, CH2 23.9, CH2 121.0, CH 25.8/26.6, CH2b 127.0, CH 23.9, CH2
11 28.0, CH3 26.6, CH3 10.7, CH3 10.9, CH3 31.1, CH3 11.2, CH3 10.7, CH3 27.2, CH3 26.7, CH3 11.2, CH3 30.9, CH3 11.3, CH3 31.3, CH3 11.2, CH3
12 12.3, CH3 12.3, CH3 12.0, CH3 12.3, CH3 13.9, CH3 12.3, CH3 12.0, CH3 12.2, CH3 12.3, CH3 12.3, CH3 13.6, CH3 28.2, CH3 13.0, CH3 12.3, CH3
13 131.7, CH 131.7, CH 131.6, CH 132.0, CH 133.9, CH 132.1, CH 131.8, CH 131.9, CH 131.8, CH 132.2, CH 134.0, CH 131.2, CH 132.9, CH 132.2, CH
14 123.9, CH2 123.9, CH2 124.0, CH2 124.0, CH2 122.5, CH2 123.3, CH2 123.8, CH2 123.7, CH2 123.8, CH2 123.3, CH2 122.4, CH2 121.7, CH2 123.2, CH2 123.3, CH2
a

Measured in CDCl3.

b

Interchangeable. 1a+d: CH3O-1: 51.7; CH3O-8a: 54.7; 1b+c: CH3O-1: 51.7; CH3O-8a: 54.5; 2a: CH3O-4a: 51.1; CH3O-8a: 52.5; 2b: CH3O-4a: 51.6; CH3O-8a: 52.9; 7: CH3O-1: 54.4; CH3O-5: 61.1; 4a+b: CH3O-8a: 51.6; 5: C2H5O-4a (interchangeable with 8a): 60.2, CH2, 14.7, CH3; C2H5O-8a (interchangeable with 4a): 59.0, CH2, 15.8, CH3; 6a: C2H5O-1 (interchangeable with 8a): 62.5, CH2, 15.7, CH3; C2H5O-8a (interchangeable with 1): 59.6, CH2, 15.5, CH3; 6b: C2H5O-1: 62.2, CH2, 15.8, CH3; C2H5O-8a: 59.6, CH2, 15.6, CH3; 7a+b: C2H5O-8a: 59.5, CH2, 15.4 CH3; 8: C2H5O-1: 62.2, CH2, 15.8, CH3; 9: C2H5O-7: 61.6, CH2, 15.6, CH3; 10: CH3-(CH2)3-O-7: 66.3 (1′-CH2), 32.4 (2′-CH2), 19.2/19.3/19.4 (3′-CH2) (interchangeable with 3″-CH2 and 3‴-CH2), 14.1 (4′-CH3); CH3-(CH2)3-O-5: 63.3 (1″-CH2), 31.8/31.9 (2″-CH2) (interchangeable with 2‴-CH2), 19.2/19.3/19.4 (3″-CH2) (interchangeable with 3′-CH2 and 3‴-CH2), 13.8/13.9 (4″-CH2) (interchangeable with 4‴-CH3); 63.6 (1‴-CH2), 31.8/31.9 (2‴-CH2) (interchangeable with 2″-CH2), 19.2/19.3/19.4 (3‴-CH2) (interchangeable with 3′-CH2 and 3″-CH2), 13.8/13.9 (4‴-CH2) (interchangeable with 4″-CH3); 11: CH3-(CH2)3-O-8a: 63.5 (1′-CH2), 31.9 (2′-CH2), 19.1 (3′-CH2), 13.7 (4′-CH3).