Table 1:
Pos. | δC, Type | δH | COSY | HMBC | ROESY |
---|---|---|---|---|---|
1 | 198.3, C | ||||
2 | 50.5, C | ||||
2-Me | 14.3, CH3 | 1.44 | 1, 2, 3 | 8, 11 | |
3 | 41.2, CH | 1.69 | 8 | 4 | 12 |
4 | 29.4, CH2 | 1.09 | 3, 5 | 6, 8 | |
2.00 | |||||
5 | 37.0, CH2 | 1.09 | 4, 6 | 3, 6, 7, 6-Me | |
1.77 | |||||
6 | 34.8, CH | 1.53 | 5, 7, 6-Me | 7, 8, 6-Me | |
6-Me | 22.9, CH3 | 0.94 | 6 | 5, 6, 7 | 6 |
7 | 43.9, CH2 | 0.87 | 5, 6, 8, 9, 6-Me | ||
1.83 | 6 | ||||
8 | 40.5, CH | 1.87 | 3, 7, 9 | 3, 9, 10 | 6, 9, 2-Me |
9 | 127.2, CH | 5.22 | 3, 7, 11, 10-Me | 8 | |
10 | 132.8, C | ||||
10-Me | 22.6, CH3 | 1.58 | 9, 10, 11 | 12 | |
11 | 50.8, CH | 3.23 | 12 | 2 | 2-Me |
12 | 132.7, CH | 5.27 | 11, 13 | 11, 14 | 3, 14, 10-Me |
13 | 133.9, CH | 5.81 | 12 | 11, 14 | |
14 | 133.4, CH | 5.93 | 15 | 13, 16 | 12 |
15 | 130.7, CH | 5.53 | 14, 16 | 14, 16, 17 | |
16 | 43.3, CH2 | 2.13 | 15, 17 | 14, 15, 17, 18 | |
2.17 | |||||
17 | 68.5, CH | 3.72 | 16, 18 | 15, 16, 18 | |
18 | 23.0, CH3 | 1.12 | 17 | 16, 17 | |
2′ | 178.1, C | ||||
3′ | 102.1, C | ||||
4′ | 192.6, C | ||||
5′ | 69.4, CH | 3.68 | 6′ | 4′ | |
6′ | 59.9, CH2 | 3.89 | 4′,5′ | ||
3.95 | |||||
N-Me | 27.3, CH3 | 3.03 | 2′, 5′ |
Recorded at 150 MHz for 13C and 600 MHz for 1H.