Table 1.
Darinskoe | Perryville | Cratheús (1950) | Kumerina | Ballinoo | Salt River | Unter Mässing | Wiley | Cratheús (Field Museum) | Parà de Minas | |
---|---|---|---|---|---|---|---|---|---|---|
Re | 1.4 ± 1.0 | 1.1 ± 0.3 | 1.0 ± 0.2 | 0.9 ± 0.2 | 0.8 ± 0.2 | 0.7 ± 0.1 | 0.4 ± 0.1 | 0.2 ± 0.1 | 0.22 ± 0.03 | 0.21 ± 0.09 |
Os | 17.4 ± 7.2 | 15.3 ± 2.9 | 12.2 ± 1.4 | 10.8 ± 2.3 | 10.9 ± 1.9 | 8.2 ± 1.3 | 4.5 ± 1.3 | 1.0 ± 0.2 | 2.8 ± 0.8 | 2.5 ± 0.3 |
W | 2.8 ± 1.3 | 1.7 ± 1.5 | 1.9 ± 0.3 | 1.7 ± 1.5 | 1.7 ± 1.2 | 1.5 ± 1.1 | 2.0 ± 0.9 | 0.7 ± 0.5 | 0.3 ± 0.1 | 0.8 ± 0.9 |
Ir | 13.7 ± 4.6 | 13.7 ± 3.0 | 10.7 ± 1.3 | 9.9 ± 1.7 | 9.6 ± 1.0 | 8.4 ± 0.6 | 5.2 ± 1.3 | 6.8 ± 1.0 | 2.3 ± 0.4 | 2.2 ± 0.4 |
Mo | 10.3 ± 4.0 | 9.0 ± 4.4 | 8.5 ± 4.8 | 9.3 ± 2.4 | 8.9 ± 4.3 | 8.0 ± 2.7 | 10.1 ± 9.6 | 13.6 ± 6.2 | 5.4 ± 0.4 | 9.0 ± 17.0 |
Ru | 15.9 ± 8.3 | 15.7 ± 5.7 | 12.5 ± 1.7 | 13.6 ± 1.3 | 11.8 ± 2.4 | 11.3 ± 0.9 | 10.2 ± 2.3 | 28.9 ± 10.8 | 4.9 ± 0.4 | 4.0 ± 0.4 |
V | 0.6 ± 0.3 | b.d. | 0.4 ± 0.9 | 0.03 ± 0.01 | 0.02 ± 0.02 | b.d. | b.d. | b.d. | 0.028 ± 0.001 | 0.2 ± 0.7 |
Pt | 17.8 ± 5.8 | 19.5 ± 3.7 | 15.0 ± 2.4 | 15.7 ± 2.2 | 14.8 ± 1.4 | 16.7 ± 1.9 | 14.2 ± 5.4 | 38.9 ± 6.0 | 6.0 ± 0.8 | 5.9 ± 0.5 |
Rh | 2.1 ± 0.8 | 2.0 ± 0.7 | 1.7 ± 0.2 | 1.8 ± 0.2 | 1.7 ± 0.2 | 1.7 ± 0.1 | 1.7 ± 0.5 | 4.0 ± 1.1 | 0.9 ± 0.3 | 0.8 ± 0.1 |
Ni | 9.7 ± 3.0 | 10.4 ± 3.1 | 9.4 ± 2.3 | 10.5 ± 2.4 | 9.5 ± 1.9 | 9.3 ± 0.4 | 10.2 ± 3.9 | 10.8 ± 2.5 | 7.4 ± 0.3 | 6.8 ± 1.2 |
Co | 0.6 ± 0.1 | 0.6 ± 0.1 | 0.57 ± 0.02 | 0.58 ± 0.02 | 0.57 ± 0.05 | 0.59 ± 0.04 | 0.57 ± 0.03 | 0.8 ± 0.1 | 0.42 ± 0.01 | 0.41 ± 0.02 |
Fea | 89.0 | 93.7 | 91.0 | 90.3 | 90.4 | 90.0 | 90.2 | 88.5 | 91.0 | 91.5 |
Pd | 3.8 ± 1.4 | 3.9 ± 1.4 | 3.0 ± 0.4 | 3.9 ± 0.9 | 3.5 ± 0.9 | 3.5 ± 0.6 | 3.7 ± 1.1 | 4.8 ± 1.9 | 3.9 ± 0.5 | 3.0 ± 0.9 |
Cr | 103 ± 56 | 143 ± 96 | 111 ± 145 | 101 ± 35 | 78 ± 51 | 66 ± 33 | 100 ± 47 | b.d. | 155 ± 5 | 34 ± 59 |
P | 0.3 ± 0.4 | 1.0 ± 1.2 | 0.5 ± 0.8 | 2.4 ± 4.5 | 1.2 ± 2.1 | 1.4 ± 2.2 | 1.5 ± 3.2 | 0.6 ± 1.0 | 0.19 ± 0.02 | 0.06 ± 0.03 |
Mn | b.d. | b.d. | 12.1 ± 22.2 | b.d. | b.d. | b.d. | b.d. | b.d. | b.d. | 1.0 ± 1.1 |
As | 7.7 ± 2.5 | 6.7 ± 2.3 | 6.2 ± 1.0 | 5.8 ± 0.3 | 7.1 ± 2.3 | 7.9 ± 2.9 | 10.2 ± 2.7 | 13.9 ± 3.4 | 3.6 ± 0.5 | 4.9 ± 2.6 |
Au | 0.8 ± 0.2 | 1.0 ± 0.1 | 0.6 ± 0.1 | b.d. | 0.8 ± 0.0 | 1.4 ± 0.2 | 1.3 ± 1.0 | 1.1 ± 0.1 | b.d. | 0.9 ± 0.1 |
Ga | 49 ± 10 | 44 ± 12 | 40 ± 5 | 42 ± 4 | 41 ± 5 | 41 ± 4 | 40 ± 6 | 45 ± 2 | 2.2 ± 0.3 | 3.7 ± 3.2 |
Ge | 112 ± 36 | 113 ± 42 | 96 ± 11 | 108 ± 11 | 101 ± 13 | 109 ± 13 | 103 ± 9 | 129 ± 10 | b.d. | b.d. |
Zn | 0.5 ± 1.6 | 0.04 ± 0.10 | 0.2 ± 0.4 | 0.1 ± 0.2 | 0.2 ± 0.3 | 0.1 ± 0.1 | 0.1 ± 0.1 | 0.02 ± 0.01 | 0.008 ± 0.004 | 0.1 ± 0.2 |
n | 5 | 6 | 8 | 6 | 7 | 6 | 13 | 6 | 6 | 4 |
Nickel, Co, and Fe concentrations reported in wt.%, all others reported in ppm.
The 2σ values reported were determined from the reproducibility of the number of lines measured (n) for each sample.
b.d. Concentration data below detection limits.
Fe data were used as an internal standard.