Table 1.
1 |
2 |
|||
---|---|---|---|---|
no. | δH, J (Hz)a | δCb | δH, J (Hz)a | δCb |
1 | 168.9 | 168.9 | ||
3 | ||||
4 | 7.83 d (7.8) | 127.9 | 7.83 d (7.8) | 127.9 |
5 | 7.49 overlapped | 131.4 | 7.54 overlapped | 131.6 |
6 | 7.21 t (7.8) | 125.1 | 7.22 overlapped | 125 |
7 | 8.45 d (7.8) | 120.8 | 8.50 d (7.8) | 120.8 |
8 | ||||
9 | 175.4 | 174.4 | ||
10 | ||||
11 | 5.04 dd (3.1, 8.7) | 50.6 | 5.04 dd (3.1, 8.70) | 50.1 |
12 | 2.51 dd (3.1, 15.0) | 39.8 | 2.50 dd (3.1, 15.0) | 38.5 |
2.77 dd (8.7, 15.0) | 2.80 dd (8.7, 15.0) | |||
13 | 76.6 | 76.5 | ||
14 | 5.26 s | 85.1 | 5.13 s | 84.2 |
15 | ||||
16 | 70.8 | 70.5 | ||
17 | 173.1 | 173 | ||
18 | ||||
19 | 137.3 | 137.3 | ||
20 | 7.48 d (7.8) | 115.1 | 7.50 overlapped | 115.1 |
21 | 7.36 t (7.8) | 129.4 | 7.39 t (7.8) | 129.5 |
22 | 7.20 t (7.8) | 123.3 | 7.21 overlapped | 123.1 |
23 | 7.53 d (7.8) | 124.5 | 7.52 overlapped | 124.3 |
24 | 137.3 | 137.3 | ||
25 | 3.97 d (3.4) | 76.2 | 3.98 d (3.4) | 76.3 |
26 | 2.18 m | 31.5 | 2.14 m | 32 |
27 | 0.85 d (7.0) | 14.8 | 0.89 d (7.0) | 15.22 |
28 | 1.05 d (7.0) | 18.2 | 1.04 d (7.0) | 18.4 |
29 | 1.38 s | 21.6 | 1.34 s | 21.8 |
30 | 1.45 s | 15.9 | 1.40 s | 15.9 |
31 | 172.6 | 172.6 | ||
32 | 3.77 s | 51.3 |
Spectra recorded at 400 MHz.
Spectra recorded at 100 MHz. Data based on 1H, 13C, HSQC, and HMBC experiments.