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. Author manuscript; available in PMC: 2021 Apr 2.
Published in final edited form as: Tetrahedron Lett. 2020 Feb 11;61(14):151730. doi: 10.1016/j.tetlet.2020.151730

Table 1.

1H and 13C NMR data of 1 and 2.

1
2
no. δH, J (Hz)a δCb δH, J (Hz)a δCb
1 168.9 168.9
3
4 7.83 d (7.8) 127.9 7.83 d (7.8) 127.9
5 7.49 overlapped 131.4 7.54 overlapped 131.6
6 7.21 t (7.8) 125.1 7.22 overlapped 125
7 8.45 d (7.8) 120.8 8.50 d (7.8) 120.8
8
9 175.4 174.4
10
11 5.04 dd (3.1, 8.7) 50.6 5.04 dd (3.1, 8.70) 50.1
12 2.51 dd (3.1, 15.0) 39.8 2.50 dd (3.1, 15.0) 38.5
2.77 dd (8.7, 15.0) 2.80 dd (8.7, 15.0)
13 76.6 76.5
14 5.26 s 85.1 5.13 s 84.2
15
16 70.8 70.5
17 173.1 173
18
19 137.3 137.3
20 7.48 d (7.8) 115.1 7.50 overlapped 115.1
21 7.36 t (7.8) 129.4 7.39 t (7.8) 129.5
22 7.20 t (7.8) 123.3 7.21 overlapped 123.1
23 7.53 d (7.8) 124.5 7.52 overlapped 124.3
24 137.3 137.3
25 3.97 d (3.4) 76.2 3.98 d (3.4) 76.3
26 2.18 m 31.5 2.14 m 32
27 0.85 d (7.0) 14.8 0.89 d (7.0) 15.22
28 1.05 d (7.0) 18.2 1.04 d (7.0) 18.4
29 1.38 s 21.6 1.34 s 21.8
30 1.45 s 15.9 1.40 s 15.9
31 172.6 172.6
32 3.77 s 51.3
a

Spectra recorded at 400 MHz.

b

Spectra recorded at 100 MHz. Data based on 1H, 13C, HSQC, and HMBC experiments.