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. 2020 Oct 26;22(11):1212. doi: 10.3390/e22111212
AS reaction surface area (m2)
cp specific heat capacity (kJ/(kg·K))
ER energy recovery rate (W)
f fugacity (Pa)
Fa area amendment factor
k dissociation rate constant (kg/(m2·Pa·s))
K intrinsic permeability (m2)
kΘC thermal conductivity (W/(m·K))
kΘRD thermal conductivity of dry porous medium (W/(m·K))
kΘRW thermal conductivity of fully saturated porous medium (W/(m·K))
kΘI thermal conductivity of ice (W/(m·K))
m mass (kg)
nH,diss mole number of dissociated hydrate (mol)
P pressure (MPa)
PWell wellbore pressure (MPa)
qB heat flow rate across the boundary (W)
QB total amount of heat transferred from the boundary (kJ)
QH total amount of hydrate dissociation heat (kJ)
QS sensible heat increase (kJ)
QS,pro sensible heat change of the produced fluid (kJ)
QS,res sensible heat change of the reservoir (kJ)
r, z cylindrical coordinates (m)
S phase saturation
t time (min)
T temperature (°C)
VP volume of the recovered methane (L)
ΔEa activation energy (J/mol)
ΔHm hydrate dissociation heat (kJ/mol)
Δs entropy production rate (W/K)
ΔS entropy production (J/K)
ΔSenv entropy production of ambient environment (J/K)
ΔSsand entropy production of quartz sand (J/K)
ΔStotal total entropy production (J/K)
Δt duration of exploitation (min)
ρ density (kg/m3)
ϕ porosity
ξ heat utilization efficiency
Subscripts and Superscripts
0 represents initial condition
B boundary
cap capillary
eq equilibrium
G gas phase
H solid hydrate phase
irA irreducible aqueous phase
irG irreducible gas
n permeability reduction exponent - Table 2
nG gas permeability reduction exponent - Table 2
s sand
W aqueous water phase