Table 2.
Surface tension and fluorescence aggregation parameters of the pure surfactants and the catanionic mixtures and ζ-potential of the mixtures.
HM | Am 1 | CMC γ 2 | γ CMC 3 | α 4 | β 5 | CMCF 2 | α 4 | β 5 | ζ-potential 6 |
---|---|---|---|---|---|---|---|---|---|
100 | 0.57 | 5.2 | 33 | 3.8 | |||||
80:20 HM | 0.28 | 0.17 | 23.5 | 0.49 | −11.3 | 0.60 | 0.49 | −5.5 | +45 |
60:40 HM | 0.26 | 0.10 | 23 | 0.458 | −12.5 | 0.47 | 0.43 | −5.4 | +43 |
50:50 HM | 0.17 | 0.096 | 23 | 0.44 | −12.3 | 0.29 | 0.41 | −7.3 | +36 |
40:60 HM | 0.22 | 0.090 | 22 | 0.43 | −12.6 | 0.31 | 0.39 | −6.7 | +33 |
20:80 HM | 0.20 | 0.12 | 22 | 0.39 | −11.9 | 0.40 | 0.32 | −5.6 | −24 |
Myr | 1.0 | 5.0 7 | 24 | 0.90 |
1 Area per molecule (Am) according to Gibbs adsorption isotherm using n = 1 in nm2, estimated error is 15%. 2 CMC obtained by surface tension (CMCγ) or Fluorescence (CMCF) in mM, estimated error is 10%. 3 Surface tension (γ) at CMC in mNm−1, estimated error is 1 mNm−1. 4 α DMHNHC14 molar fraction in the micelles. 5 Interaction parameter (β). 6 ζ-potential in mV, estimated error is 2 mV. 7 This is close to the solubility limit in our experiments.