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. 2020 Nov 27;8:592056. doi: 10.3389/fchem.2020.592056

Table 2.

Performance of typical pollutants under different reaction conditions.

Pollutants Reaction systems Performances References
PPCPs Carbamazepine (CBZ) LaCoO3/PMS • LaCoO3 calcinated at 600°C showed the best performance
• 91.8% of carbamazepine (100 mg/L) was removed within 30 min at pH 6–8
• First-order kinetics
Guo et al., 2020
Levofloxacin hydrochloride (LVF) CoFeO2@CN/PMS • CoFeO2@CN/PMS performed better than CoFeO2@CN and PMS
• 89.4% of LVF (10 mg/L) was removed in 20 min using 0.2 g/L catalyst and 0.5 mM PMS
Pi et al., 2020
Ibuprofen (IBP) N-doped graphene aerogel (NGA)/PMS • Catalytic activity increase exhibited NGA>NrGO>GA
• 100% of 20 mg/L IBP was removed in 60 min at 45°C
• Pseudo-first-order kinetics with activation energy of 87.5 kJ/mol
Wang et al., 2019
Sulfachloropyridazine (SCP) Ni@NPC/PS • Catalytic activity of Ni@NPC>GO>N-rGO>MWCNTs
• 100% of SCP (>99%) was removed in 30 min at 45°C
Kang et al., 2019
Ketoprofen (KET) Heat/PS • 100% of 10 μM KET was removed in 60 min at pH = 3
• 97.3% of 10 μM KET was removed in 60 min at pH = 7
• 69.4% of 10 μM KET was removed in 60 min at pH = 10
• Pseudo-first-order kinetics with activation energy of 169.74 kJ/mol
Feng et al., 2017b
Caffeine (CAF) Co-MCM41/PMS • Co-MCM41/PMS performed better than CoO/PMS or Co3O4/PMS
• 100% of 0.05 mM CAF was removed in 20 min using 200 mg/L catalyst and 0.2 mM PMS
Qi et al., 2013
Diclofenac (DCF) BFO/PMS • 65.4% of 0.025 mM DCF was removed in 60 min at pH 3.0 using 0.5 mM PMS and 0.3 g/L BFO
• Following two separate concurrent pseudo-first-order catalytic process with different decay rates
Han et al., 2020
Sulfonamides (SAs) Heat/PS • Conditions: reaction time 3 h, reaction temperature 60°C, 2 mM PS and 30 μM SAs, the removal rate of SMX, SIX, STZ, and SMT were 98, 100, 97, and 81%, respectively
• Pseudo-first-order kinetics with the activation energy of 109.8 ± 14.7, 133.9 ± 9.5, 130.8 ± 1.1, and 106.2 ± 3.5 kJ/mol for SMX, SIX, STZ, and SMT, respectively
Zhou et al., 2019
EDCs Bisphenol A (BPA) Magnetic CFA/PS • 76.9% of 0.22 mmol/L BPA was removed at 20°C and pH 5 in 60 min using 2 g/L magnetic CFA and 22 mM PS
• Pseudo-first-order kinetics
Xu et al., 2019
• 76.5% of 0.22 mmol/L BPA was removed at 20°C and pH 5 in 60 min using 2 g/L magnetic CFA and 22 mM PS
• Pseudo-first-order kinetics
• 70.2% of 0.22 mmol/L BPA was removed at 20°C and pH 5 in 60 min using 2 g/L magnetic CFA and 22 mM PS
• Pseudo-first-order kinetics
Bisphenol A (BPA) CoS@GN-60/PMS • 92% of 20 mg/L BPA was removed at pH 6.65 in 8 min using 0.1 g/L catalysts and 0.1 g/L PMS
• First-order kinetics
Zhu et al., 2019
Bisphenol F (BPF) Sr2FeCoO6/PMS • Catalytic activity of Sr2FeCoO6>SrCoO3>SrFeO3
• 100% of 20 mg/L BPF was removed at 55°C using 0.45 g/L Sr2FeCoO6 and 0.2 mM PMS
• Pseudo-first-order kinetics
Hammouda et al., 2018
Tetrabromobisphenol A (TBBPA) Co(II)/PMS • More than 96% of 9.2 μM TBBPA was removed at 20°C and pH 8.0 using 0.5 μM Co(II) and 0.2 mM PMS
• Pseudo-first-order kinetics
Ji et al., 2016a
DBPs Iohexol Co(II)/PMS • Almost 100% of 50 μM iohexol was removed in 30 min at 25°C and pH 7.0 using 4 mM PMS
• Pseudo-first-order kinetics
Zhao et al., 2019
Bromide UV/PMS • 100% of bromide (initial concentration of 20 μM) was removal in 20 min at pH 7.0 and UV intensity 2.19 μE L−1 s−1 using ≥300 μM PS
• Follow pseudo-zero-order kinetics
Fang and Shang, 2012
HCOMs Metolachlor (MET) Co(II)/PMS • 100% of 10 mg/L MET was removed in 40 min at 25°C and pH 6.5 using 0.2 g/L CoFe2O4 and 3 mM PMS Liu C. et al., 2019
Clopyralid (CLP) Heat/PS • The removal rate of CLP increased with increasing PS concentration
• 57 and 74% of CLP were removed at 50°C when the initial PS concentration was 1.0 and 2.0 mM, respectively
Yang et al., 2020
Landfill leachate Heat/PS • Acidic condition favored persulfate oxidation of leachate organics
• High persulfate dose (PS:12COD0) and high temperature enhanced the removal of COD and ammonia nitrogen
• 100% of ammonia nitrogen was removed at 50°C and pH 5.3 when persulfate dose was 2
• 91% of COD was removed at 50°C and pH 4 when persulfate dose was 2
Deng and Ezyske, 2011