Table 1.

The VOC emission pattern detected using a SPME-GC/MS method in the headspace atmosphere of samples tested at BUT. Similarity indices (SI) were obtained by comparing a profile of the EI mass spectrum of a given VOC compound with the reference one in NIST Mass Spectral Database library; these values represent the confidence in the molecular identification.

tR 1 [min]	SI 2 %	RIExp 3	RILit 4	Ref.	Peak Area per Treatment	Name of Compound 5
				(1) Empty Container
7.19	65	902	901	[29]	17,674,234	Heptanal ++a
10.05	80	1003	998	[29]	40,444,566	Octanal ++a
10.82	28	1029	1027	[30]	21,189,032	2-Ethyl-hexanol a
13.05	79	1104	1100	[29]	76,538,207	Nonanal ++a
15.98	53	1206	1201	[29]	14,513,924	Decanal ++a
18.06	−	1281	−	−	14,724,741	Unknown compound
18.77	−	1307	−	−	13,630,063	Unknown compound
21.21	32	1400	1400	[29]	6,427,563	Tetradecane ++a
21.44	58	1409	1408	[29]	17,444,416	Dodecanal ++a
24.07	78	1516	1514	[31]	47,388,559	Butylated Hydroxytoluene ++a
					(2) PDA Medium
4.77	50	804	801	[29]	19,939,473	Hexanal +a
5.48	57	834	828	[29]	11,223,384	Furfural +a
7.18	31	902	901	[29]	39,366,443	Heptanal ++a
8.80	72	959	952	[29]	60,063,839	Benzaldehyde a
9.74	87	992	984	[29]	31,027,584	2-Pentyl-furan b
10.05	74	1003	998	[29]	11,751,703	Octanal ++a
10.81	44	1029	1027	[30]	32,462,061	2-Ethyl-hexanol a
11.23	73	1043	1036	[29]	73,539,705	Benzeneacetaldehyde ++a
12.96	21	1101	1100	[29]	12,884,326	Undecane +a
13.04	80	1104	1100	[29]	41,840,277	Nonanal ++a
15.48	−	1189	−	−	4,687,953	Unknown compound
15.83	30	1201	1200	[29]	4,893,511	Dodecane +a
15.97	50	1206	1201	[29]	10,723,873	Decanal ++a
18.13	−	1284	−	−	5,876,115	Unknown compound
18.77	−	1307	−	−	4,815,975	Unknown compound
21.43	44	1409	1408	[29]	11,027,672	Dodecanal ++a
24.06	74	1515	1514	[31]	14,730,122	Butylated Hydroxytoluene ++a
					(3) A. gallica
8.80	47	959	n/a6	−	300,374,347	(2E)-4,4-Dimethyl-2-pentenal c
11.73	53	1060	1049	[29]	62,813,700	(E)-2-Octen-1-al b
20.87	10	1387	n/a	-	611,543,126	1,3,4,5,6,7-Hexahydro-2,5,5-trimethyl-2H-2,4a-ethanonaphthalene c
23.89	26	1506	1506	[29]	74,690,325	(Z)-α-Bisabolene +a
					(4) A. ostoyae
8.80	49	959	n/a	-	87,776,838	(2E)-4,4-Dimethyl-2-pentenal c
11.74	35	1060	1049	[29]	20,166,139	(E)-2-Octen-1-al b
18.49	21	1297	1293	[29]	8,070,650	2-Undecanone a
20.83	43	1386	n/a	-	106,170,662	1,3,4,5,6,7-Hexahydro-2,5,5-trimethyl-2H-2,4a-ethanonaphthalene c
22.49	59	1451	1440	[29]	43,908,793	β-Barbatene a
24.42	34	1531	1522	[29]	24,134,794	δ-Cadinene +a
					(5) F. avenaceum
3.28	76	712	735	[32]	2,653,753	2,4-Dimethylfuran +b
9.13	23	971	970	[33]	3,974,721	Mesitilene +a
10.91	76	1032	1029	[29]	9,540,610	β-Phellandrene a
21.59	35	1415	1407	[29]	11,961,247	Longifolene a
24.46	73	1532	1519	[29]	3,401,805	β-Bazzanene +a
				(6) F. culmorum
1.62	77	<500	448	[34]	163,586,144	Ethanol a
2.25	96	573	606	[29]	45,234,113	Ethyl acetate +a
3.55	41	728	731	[29]	6,085,804	Isoamyl alcohol +a
3.61	56	732	724	[29]	3,371,660	2-Methyl-butanol a
10.91	18	1032	1029	[29]	177,256,946	β-Phellandrene a
21.80	43	1424	1408	[29]	20,993,355	Acora-3,7(14)-diene +b
22.23	man.7	1441	1432	[29]	138,760,275	β-Copaene +a
					(7) F. oxysporum
6.02	78	854	864	[35]	845,609	2-Furanmethanol +b
7.96	59	930	927	[36]	2,621,568	Hexyl formate +a
8.86	79	961	952	[29]	49,523,292	Benzaldehyde +a
9.65	68	989	979	[29]	5,057,096	3-Octanone a
10.27	71	1010	960	[29]	2,393,859	Isoamyl propionate +a
10.90	54	1032	n/a	−	63,835,818	Heptyl formate +a
21.98	33	1431	1419	[29]	4,969,490	β-Cedrene a
22.49	90	1451	n/a	−	23,065,220	3-Chloro-4-methoxy-benzaldehyde c
22.77	20	1463	n/a	−	8,382,097	2,4-Dichloro-3-methoxy-1-benzene carbonyl chloride +c
23.34	93	1486	864	[35]	2,740,362	3,4-Dimethoxy-benzaldehyde +a
					(8) F. poae
9.43	81	981	974	[29]	93,704,125	1-Octen-3-ol a
9.79	36	994	988	[29]	166,758,547	Myrcene +a
13.39	59	1116	1122	[37]	100,643,564	1-Ethyl-4-methoxy-benzene b
16.68	41	1231	1223	[29]	36,663,640	Citronellol +a
20.10	28	1358	1350	[29]	106,101,600	α-Longipinene +a
20.65	16	1379	1371	[29]	108,987,407	Longicyclene +a
21.43	man.	1409	1400	[29]	248,606,376	β-Longipinene +b
21.65	37	1418	1407	[29]	1,390,824,920	Longifolene a
21.81	−	1427	−	−	482,683,621	Unknown sesquiterpene
21.91	22	1428	1419	[29]	195,664,192	β-Ylangene +a
22.31	−	1444	−	−	954,381,082	Unknown sesquiterpene
22.55	55	1454	1440	[29]	129,567,010	β-Barbatene +a
22.68	16	1459	1449	[29]	117,848,857	α-Himachalene +a
22.75	50	1462	1454	[29]	143,907,373	(E)-β-Farnesene +a
23.02	20	1473	1466	[29]	116,555,130	α-Acoradiene +a
23.38	16	1487	1481	[29]	134,783,119	γ-Himachalene +a
23.98	43	1512	n/a	−	44,779,678	8-Isopropenyl-1,5-dimethyl-1,5-cyclodecadiene +c
24.05	17	1515	1505	[29]	51,262,732	β-Bisabolene +a
25.03	−	1557	−	−	42,987,721	Unknown sesquiterpene
26.31	60	1612	1599	[29]	1,576,920,976	Longiborneol +a
				(9) P. cactorum
1.71	86	<500	500	[34]	5,827,788	Acetone a
3.75	97	740	744	[38]	4,459,515	Dimethyl disulfide b
4.12	−	763	−	−	4,321,348	Unknown compound
6.35	60	868	863	[29]	25,809,441	1-Hexanol +a
9.15	58	971	959	[29]	5,111,166	1-Heptanol +a
9.42	75	981	974	[29]	19,848,783	1-Octen-3-ol a
9.65	76	989	979	[29]	12,627,315	3-Octanone a
9.81	88	995	984	[29]	4,284,441	2-Pentyl-furana
12.05	22	1071	1060	[29]	2,508,277	2-Octen-1-ol +a
12.13	19	1073	1063	[29]	4,044,266	1-Octanol +a
				(10) P. cinnamomi
1.61	97	<500	448	[31]	9,483,339	Ethanol a
9.43	56	981	974	[29]	2,215,655	1-Octen-3-ol a
10.88	47	1031	1027	[30]	5,251,305	2-Ethyl-hexanol a
18.13	85	1284	1282	[39]	1,001,882	4-Ethyl-2-methoxy-phenol +b
				(11) P. plurivora
1.71	84	<500	500	[34]	4,481,938	Acetone a
3.20	64	707	711	[40]	2,268,583	Acetoin +a
6.37	36	869	863	[29]	1,803,069	Hexanol +a
7.51	76	914	933	[41]	3,627,373	4-Hydroxy-butanoic acid +b
8.14	16	936	932	[29]	1,684,400	α-Pinene +a
10.35	14	1013	1008	[29]	1,103,050	Δ-3-Carene +a
				(12) P. ramorum
1.16	98	<500	448	[34]	20,885,799	Ethanol a
3.55	74	728	730	[42]	80,424,948	3-Methyl-butanol a
3.61	74	732	724	[29]	26,123,097	2-Methyl-butanol a
9.43	72	981	974	[29]	8,370,575	1-Octen-3-ol a
9.65	70	989	979	[29]	11,144,929	3-Octanone a
13.37	87	1116	1106	[29]	48,377,677	2-Phenylethanol +a
					(13) R. solani
1.71	87	<500	500	[34]	3,565,392	Acetone a
9.42	74	981	974	[29]	24,589,405	1-Octen-3-ol a
9.65	62	989	979	[29]	3,438,485	3-Octanone a
9.90	75	998	988	[29]	6,372,403	3-Octanol +a
15.56	−	1191	-	-	4,474,717	Unknown compound
				(14) T. asperellum
1.71	82	<500	500	[34]	3,920,210	Acetonea
3.56	62	729	730	[41]	7,870,509	3-Methyl-butanola
3.62	45	733	724	[29]	4,424,960	2-Methyl-butanola
3.76	98	741	744	[38]	11,829,339	Dimethyl disulfideb
7.26	−	905	−	−	153,721,663	Unknown compound
13.01	−	1103	−	−	20,319,451	Unknown compound
13.38	85	1116	1106	[29]	37,177,146	2-Phenyethanol +a
20.08	−	1357	−	−	70,272,034	Unknown sesquiterpene
20.91	44	1389	1380	[29]	229,806,310	Daucene +b
21.81	man.	1424	1412	[29]	25,748,186	2-epi-β-Funebrene +b
21.98	50	1431	1419	[29]	86,596,372	β-Cedrenea
23.93	28	1510	1500	[29]	118,470,969	Isodaucene +b
24.27	21	1524	1513	[29]	52,189,482	γ-Cadinene +a
24.63	40	1540	1530	[29]	194,592,295	Dauca-4(11)-8-diene +a
25.49	−	1576	−	−	8,894,971	Unknown sesquiterpene
27.81	−	1679	−	−	15,501,124	Unknown sesquiterpene
28.31	27	1701	n/a	−	15,437,838	1-Isopropyl-4,8-dimethylspiro [4.5]dec-8-en-7-one +c
30.26	−	1793	−	−	21,104,266	Unknown sesquiterpene

¹ retention time; ² similarity index; ³ Kovats retention index calculated from experimental data; ⁴ Kovats retention index from literature; ⁵ compound exclusively present there (+) or present only in controls (++); ⁶ data not available; ⁷ manual matching; ^a compound identified using retention time of authentic standard, matching with MS library and comparison with reported KI; ^b compound identified by matching with MS library and comparison with reported KI; ^c compound identified by matching with MS library.