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. 2020 Dec 4;21(23):9266. doi: 10.3390/ijms21239266

Figure 11.

Figure 11

From Figure 10, the water and the O2 molecules were eliminated and the remaining species contains a catechol moiety. Hence, a potential approach of another superoxide is able to sequester a H atom, d(O2-H) = 0.998 Å, forming the O2H species. This is the classical manner of scavenging radicals by polyphenols, (option a). Total charge is −1, due to O2H. Interestingly, the O2H species in turn can capture a proton to form H2O2.