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. 2020 Dec 9;16:3015–3031. doi: 10.3762/bjoc.16.251

Scheme 2.

Scheme 2

(A) An intramolecular trimethylenemethane diyl [3 + 2] cycloaddition with allenyl diazo compound 38 as a key intermediate to give angular-fused triquinane 41 [29]. (B) Synthesis of (−)-crinipellin A (15) [30]. (C) Synthesis of waihoensene (16) [31].