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. Author manuscript; available in PMC: 2021 Jul 8.
Published in final edited form as: J Am Chem Soc. 2020 Jun 24;142(27):11674–11679. doi: 10.1021/jacs.0c04533

Scheme 3.

Scheme 3.

Transformations of Si–H insertion productsa

a Isolated yields; dr determined using 1H NMR spectroscopy; er determined using CSP-HPLC. bIsolated as a 85:15 (major) mixture with the hydrosilylation product. See SI for more information. cdr determined using 19F NMR spectroscopy.