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. 2020 Sep 23;59(48):21656–21662. doi: 10.1002/anie.202008622

Table 1.

FeIV−O bond lengths from various structure determinations of peroxidases. For DtpB, the range of bond lengths observed for the monomers in the asymmetric unit are given.

Peroxidase

(temperature [K])

Compound I

FeIV−O [Å]

Compound II

FeIV−O [Å]

DtpB (RT)

1.65–1.89

DtpB (100 K)

1.65–1.84

APX (100 K)

1.72 [3c]

1.84 [3c]

1.88 [4b]

HRP (100 K)

1.70 [3a]

1.83 [3a]

CcP (100 K)

1.62 [3c]

1.83 [3c]

1.72 [3b]

1.60 [4a]

1.70 [5a]