Table 7. Selected Bond Lengths [Å] and Bond Angles [deg] for Compounds C1 and C3a.
| C1 | C3 | ||
|---|---|---|---|
| Pd(1)–C(1)#2 | 1.997(3) | Pd(1)–C(1) | 1.964(8) |
| Pd(1)–C(1) | 1.997(3) | Pd(1)–Br(1) | 2.4659(11) |
| Pd(1)–Br(1) | 2.4906(4) | Pd(2)–C(17) | 1.985(8) |
| Pd(1)–Br(1)#2 | 2.4906(4) | Pd(2)–Br(2) | 2.4704(11) |
| C(1)–N(2) | 1.344(4) | N(1)–C(1) | 1.352(10) |
| C(1)–N(1) | 1.350(4) | N(1)–C(9) | 1.395(10) |
| C(2)–N(1) | 1.397(4) | N(2)–C(1) | 1.355(9) |
| C(7)–N(2) | 1.388(4) | N(2)–C(14) | 1.372(9) |
| C(8)–N(1) | 1.475(4) | N(2)–C(15) | 1.458(9) |
| C(11)–N(2) | 1.469(4) | N(3)–C(17) | 1.339(10) |
| N(3)–C(25) | 1.373(9) | ||
| N(3)–C(18) | 1.463(9) | ||
| N(4)–C(17) | 1.339(8) | ||
| N(4)–C(30) | 1.401(9) | ||
| N(4)–C(31) | 1.452(9) | ||
| C(1)#2–Pd(1)–C(1) | 88.66(17) | C(1)–Pd1–C(1)#1 | 87.4(3) |
| C(1)#2–Pd(1)–Br(1) | 177.48(8) | C(1)–Pd(1)–Br(1) | 175.0(2) |
| C(1)–Pd(1)–Br(1) | 89.17(8) | C(1)#1–Pd(1)–Br(1) | 88.5(2) |
| C(1)#2–Pd(1)–Br(1)#2 | 89.17(8) | Br1–Pd1–Br1#1 | 95.49(4) |
| C(1)–Pd(1)–Br(1)#2 | 177.48(8) | C(17)#2–Pd(2)–C(17) | 87.7(3) |
| Br(1)–Pd(1)–Br(1)#2 | 92.97(2) | Br2#2–Pd(2)–Br(2) | 97.01(4) |
| C(17)–Pd(2)–Br(2) | 175.2(2) | ||
| C(17)#2–Pd(2)–Br(2) | 87.6(2) | ||
a
Symmetry codes: #1 = x, −y + 3/2, z #2 = x, −y + 1/2, z.