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(a) X-ray crystal structure of AMMVN⊂Pt-41 and diagram of encapsulated radical initiators. (b) Addition of the confined initiator (red) to an organic solution of monomers induces the spontaneous release of the initiator from the capsule and the polymerization initiates by light or thermal stimuli. (b) Adapted with permission from ref (77). Copyright 2014 Springer Nature.
