Table 1.
Pos. | δC, mult | δH, (J in Hz) | HMBC | COSY |
---|---|---|---|---|
1 | 141.3, C | |||
2 | 116.7, C | |||
3 | 138.4, C | |||
4 | 144.9, C | |||
5 | 121.6, C | |||
6 | 139.1, C | |||
6-OMe | 61.5, CH3 | 4.12, s | 6 | |
3-OMe | 60.4, CH3 | 3.58, s | 3 | |
2’ | 104.6, CH | 6.24, s | 4, 5, 3’, 3a’, 7a’ | |
3’ | 90.3, C | |||
3a’ | 129.7, C | |||
4’ | 125.0, CH | 7.78, d (7.5) | 3’, 6’, 7’, 7a’ | 5’ |
5’ | 120.1, CH | 6.88, t (7.5) | 3a’, 4’, 7’ | 4’, 6’ |
6’ | 130.1, CH | 7.18, t (7.8) | 3a’, 4’, 7’, 7a’ | 5’, 7’ |
7’ | 109.9, CH | 6.70, d (8.0) | 3a’, 5’ | 6’ |
7a’ | 148.6, C | |||
1” | (NH) | 8.44, brs | 3” | 2” |
2” | 124.8, CH | 7.29, d (2.4) | 2, 3”, 3a’’, 7a’’ | 3’’ |
3” | 106.7, C | |||
3a’’ | 126.5, C | |||
4” | 120.3, CH | 7.47, d (8.1) | 3”, 3a’’, 5”, 6”, 7”, 7a’’ | 5’’ |
5” | 120.4, CH | 7.14, t (7.5) | 3a’’, 7” | 4’’, 6’’ |
6” | 122.7, CH | 7.24, t (7.8) | 4”, 7a’’ | 5’’, 7’’ |
7” | 111.4, CH | 7.43, d (8.1) | 3a’’, 5”, 6” | 6’’ |
7a’’ | 136.2, C | |||
1-OH | 5.06, brs | 1, 2, 6 |