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. 2020 Nov 30;18(12):608. doi: 10.3390/md18120608

Table 1.

1H and 13C NMR spectroscopic data (δ in ppm, CDCl3) for 6.

Pos. δC, mult δH, (J in Hz) HMBC COSY
1 141.3, C
2 116.7, C
3 138.4, C
4 144.9, C
5 121.6, C
6 139.1, C
6-OMe 61.5, CH3 4.12, s 6
3-OMe 60.4, CH3 3.58, s 3
2’ 104.6, CH 6.24, s 4, 5, 3’, 3a’, 7a’
3’ 90.3, C
3a’ 129.7, C
4’ 125.0, CH 7.78, d (7.5) 3’, 6’, 7’, 7a’ 5’
5’ 120.1, CH 6.88, t (7.5) 3a’, 4’, 7’ 4’, 6’
6’ 130.1, CH 7.18, t (7.8) 3a’, 4’, 7’, 7a’ 5’, 7’
7’ 109.9, CH 6.70, d (8.0) 3a’, 5’ 6’
7a’ 148.6, C
1” (NH) 8.44, brs 3” 2”
2” 124.8, CH 7.29, d (2.4) 2, 3”, 3a’’, 7a’’ 3’’
3” 106.7, C
3a’’ 126.5, C
4” 120.3, CH 7.47, d (8.1) 3”, 3a’’, 5”, 6”, 7”, 7a’’ 5’’
5” 120.4, CH 7.14, t (7.5) 3a’’, 7” 4’’, 6’’
6” 122.7, CH 7.24, t (7.8) 4”, 7a’’ 5’’, 7’’
7” 111.4, CH 7.43, d (8.1) 3a’’, 5”, 6” 6’’
7a’’ 136.2, C
1-OH 5.06, brs 1, 2, 6