Table 3.
UHPLC-HRMS and GC-MS MS parameters and relative retention time (RRt) in targeted MS/MS and SIM mode, respectively.
| UHPLC-HRMS | GC-MS | ||||||
|---|---|---|---|---|---|---|---|
| Analytes | Chemical Formula | RRt (min) |
Quantifier (m/z) [M + H]+ |
Qualifiers (m/z) |
RT (min) |
Quantifier (m/z) | Qualifiers (m/z) |
| JWH-122 | C25H25NO | 1.03 | 356.2008 | 169.0646 214.1223 |
13.9 | 298 | 214 284 |
| JWH-122 N-(4-OH) | C25H25NO2 | 0.84 | 372.1949 | 141.0698 169.0649 |
- | - | - |
| JWH-122 N-(5-OH) | C25H25NO2 | 0.85 | 372.1951 | 141.0698 169.0647 |
- | - | - |
| JWH-210 | C26H27NO | 1.06 | 370.2157 | 183.0803 214.1222 |
14.8 | 214 | 144 183 |
| JWH-210 N-(4-OH) | C26H27NO2 | 0.88 | 386.2105 | 144.0443 183.0806 |
- | - | - |
| JWH-210 N-(5-OH) | C26H27NO2 | 0.89 | 386.2106 | 183.0803 230.1172 |
- | - | - |
| UR-144 | C21H29NO | 0.96 | 312.2325 | 125.0961 244.0963 |
7.1 | 214 | 144 296 |
| UR-144 N-(5-OH) | C21H29NO2 | 0.78 | 328.2271 | 125.0961 230.1172 |
- | - | - |
| JWH-018-d11 | C24H12D11NO | 1.00 | 353.2537 | - | 11.99 | 352 | - |