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(a) ERED catalyzed radical dehalogenation using Gluconobacter oxydans ene-reductase (GluER). (b) Semiquinone enabled redox neutral radical cyclization with 12-oxophytodienoate reductase 1 (OPR1). (c) Photoinduced reductive cyclization with GluER. (d) Deacetoxylation via enzymatic redox activation using the NADPH dependent double bond reductase from Nicotiana tabacum (NtDBR).
