TABLE 1.
Batch | Durationa (h) | Average currenta (mA) | Yield (mol mol–1 lactate consumed) |
Highest production rate (mM d–1) |
|||||
Propionate | Acetate | Butyrateb | Propionate | Acetate | Butyrateb | ||||
LB1 | I | 158.4 | 2.19 | 0.39 | 0.32 | − | 4.49 | 2.67 | − |
II | 120.0 | 5.39 | 0.23 | 0.31 | − | 2.2 | 1.71 | − | |
III | 148.8 | 6.5 | 0.28 | 0.36 | − | 2.76 | 2.25 | − | |
IV | 139.2 | 7.68 | 0.18 | 0.23 | − | 1.87 | 1.00 | − | |
LB2 | I | 158.4 | 2.42 | 0.17 | 0.18 | − | 1.98 | 1.39 | − |
II | 120.0 | 3.62 | 0.21 | 0.18 | − | 4.96 | 3.91 | − | |
III | 148.8 | 4.51 | 0.16 | 0.35 | − | 2.12 | 2.81 | − | |
IV | 139.2 | 5.43 | 0.19 | 0.10 | − | 3.13 | 1.27 | − | |
L1 | I | 146.4 | 1.28 | 0.28 | 0.28 | 0.00 | 4.74 | 2.55 | 0 |
II | 244.8 | 2.03 | 0.30 | 0.39 | 0.02 | 7.2 | 5.13 | 0.14 | |
L2 | I | 146.4 | 2.08 | 0.37 | 0.34 | 0.00 | 5.86 | 2.83 | 0 |
II | 244.8 | 5.44 | 0.28 | 0.30 | 0.02 | 6.16 | 4.44 | 0.12 | |
L3 | I | 381.6 | 2.18 | 0.48 | 0.30 | 0.08 | 12.88 | 7.22 | 1.26 |
CLB1_pH5 | I | 285.0 | None | 0.03 | 0.10 | − | 0.04 | 0.20 | − |
CLB2_pH5 | I | 285.0 | None | 0.02 | 0.34 | − | 0.07 | 0.48 | − |
CLB1_pH7 | I | 285.0 | None | 0.44 | 0.42 | − | 2.53 | 1.53 | − |
CLB2_pH7 | I | 285.0 | None | 0.39 | 0.42 | − | 2.40 | 1.65 | − |
CL1_pH5 | I | 285.0 | None | 0.25 | 0.28 | 0.19 | 1.67 | 2.07 | 0.80 |
CL2_pH5 | I | 285.0 | None | 0.16 | 0.37 | 0.22 | 0.82 | 1.15 | 0.96 |
CL1_pH7 | I | 285.0 | None | 0.36 | 0.37 | 0.00 | 2.78 | 1.47 | 0.09 |
CL2_pH7 | I | 285.0 | None | 0.45 | 0.36 | 0.01 | 3.94 | 2.08 | 0.08 |
For EF experiments, the data reported include carboxylates detected in the catholyte and anolyte. CLB and CL refer to the non-electrochemical control experiments with lactate and butyrate, or only lactate, as substrate, respectively.
aThe start-up period at −1.2 V applied potential was excluded.
bButyrate yield and production rate are not included for LB1, LB2, CLB2, or CLB2 because butyrate was added at the beginning of the experiment.