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. Author manuscript; available in PMC: 2020 Dec 29.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Aug 24;59(43):18898–18919. doi: 10.1002/anie.201915657

Scheme 6.

Scheme 6.

A) Retrosynthesis and B) total synthesis of (−)-xishacorene B. AIBN = azobis(isobutyronitrile), Cy = cyclohexyl, PCC = pyridinium chlorochromate.