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. Author manuscript; available in PMC: 2020 Dec 29.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Aug 24;59(43):18898–18919. doi: 10.1002/anie.201915657

Scheme 12.

Scheme 12.

Total synthesis of rhodomollein XX and XXII. acac = acetylacetonato, DMAP = 4-(dimethylamino)pyridine, LDA = lithium diisopropyl-amide, PPTS = pyridinium p-toluenesulfonate, pyr = pyridine, TMS = trimethylsilyl, TsOH = para-toluenesulfonic acid.