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. Author manuscript; available in PMC: 2020 Dec 29.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Aug 24;59(43):18898–18919. doi: 10.1002/anie.201915657

Scheme 18.

Scheme 18.

Syntheses of (−)-aspewentins A–C according to Stoltz and co-workers. PHOX = phosphinooxazolines, Bz2O = benzoic anhydride, cap = caprolactamate, nbd = norbornadiene, DIBALH = diisobutylaluminum hydride, TBHP = tert-butyl hydroperoxide, TEMPO = 2,2,6,6-tetra-methylpiperidinyloxyl.