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. Author manuscript; available in PMC: 2020 Dec 29.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Aug 24;59(43):18898–18919. doi: 10.1002/anie.201915657

Scheme 23.

Scheme 23.

Synthesis of sesquicillin A (152) by Baran and co-workers. PHOX = phosphinooxazolines, Sia2BH = disiamylborane. (−)-effusin. HG-II = Hoveyda-Grubbs