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. 2020 Dec 17;142(52):21628–21633. doi: 10.1021/jacs.0c10884

Scheme 5. Hydrogenation of Thioesters Based on Various Thiols.

Scheme 5

Conditions: Same as Scheme 4.

40 bar H2.

>90% conversion.

150 °C.

In the presence of 2% hexanethiol.