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. 2020 Dec 11;11(1):43–59. doi: 10.1021/acscatal.0c04290

Table 4. Full XPS Quantification in at.% of All Studied Catalysts after Selected DRM Treatments Based on the Deconvolution Profiles of Figure S14.

  La1.8Ba0.2NiO4
La2Ni0.8Cu0.2O4
La1.8Ba0.2Ni0.9Cu0.1O4
XPS fitting data (atom %) of Ni 3p region for catalysts 3p 3/2 (Ni3+) 3p 3/2 (Ni2+) 3p 3/2 (Ni0) 3p 3/2 (Ni3+) 3p 3/2 (Ni2+) 3p 3/2 (Ni0) 3p 3/2 (Ni3+) 3p 3/2 (Ni2+) 3p 3/2 (Ni0)
before DRM 19.99 80.01 0 0 100 0 18.03 81.97 0
cooled down at 770 °C - - - 0 75.12 24.88 13.92 63.28 22.8
after keeping at 800 °C for 30 min 10.55 42.18 47.27 0 60 40 0 60.45 39.55
after keeping at 800 °C for 90 min 7.29 36.46 56.25 0 49.11 50.89 0 51.44 48.56