| Crystal data |
| Chemical formula |
K+·C12H8BF2O−
|
2C24H20P+·2C12H8BF2O−·3C2H3N |
|
M
r
|
256.09 |
1235.89 |
| Crystal system, space group |
Monoclinic, P21/c
|
Triclinic, P
|
| Temperature (K) |
173 |
173 |
|
a, b, c (Å) |
13.2962 (10), 6.2300 (4), 12.9294 (11) |
10.3527 (4), 13.5958 (5), 23.4352 (9) |
| α, β, γ (°) |
90, 97.226 (6), 90 |
86.218 (3), 78.916 (3), 87.104 (3) |
|
V (Å3) |
1062.50 (14) |
3227.6 (2) |
|
Z
|
4 |
2 |
| Radiation type |
Mo Kα |
Mo Kα |
| μ (mm−1) |
0.50 |
0.13 |
| Crystal size (mm) |
0.48 × 0.46 × 0.23 |
0.42 × 0.38 × 0.29 |
| |
| Data collection |
| Diffractometer |
Stoe IPDS II two-circle |
Stoe IPDS II two-circle |
| Absorption correction |
Multi-scan (X-AREA; Stoe & Cie, 2001 ▸) |
Multi-scan (X-AREA; Stoe & Cie, 2001 ▸) |
|
T
min, T
max
|
0.794, 0.893 |
0.947, 0.963 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
6459, 1980, 1796 |
47827, 11854, 10863 |
|
R
int
|
0.050 |
0.040 |
| (sin θ/λ)max (Å−1) |
0.607 |
0.604 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.030, 0.083, 1.06 |
0.041, 0.109, 1.05 |
| No. of reflections |
1980 |
11854 |
| No. of parameters |
154 |
842 |
| H-atom treatment |
H-atom parameters constrained |
H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) |
0.26, −0.43 |
0.48, −0.44 |
